10.18453/rosdok_id00000409
Hollmann, Dirk
Dirk
Hollmann
http://d-nb.info/gnd/137495889
New applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studies
Universität Rostock
2008
540 Chemistry & allied sciences
2008
en
http://purl.uni-rostock.de/rosdok/id00000409
urn:nbn:de:gbv:28-diss2009-0012-1
This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed.