10.18453/rosdok_id00001428
Siyo, Baraa
Baraa
Siyo
http://d-nb.info/gnd/1060564440
Development of palladium nanoparticles based catalysts for aerobic oxidation of 5-hydroxymethylfurfural and glycerol
Universität Rostock
2014
540 Chemistry & allied sciences
2014
en
http://purl.uni-rostock.de/rosdok/id00001428
urn:nbn:de:gbv:28-diss2014-0180-6
Palladium nanoparticles were synthesized by the polyol method. The prepared NPs were deposited onto supports and applied in 5-hydroxymethylfurfural (HMF) and glycerol (GLY) oxidation. A high yield of 2,5-furandicarboxylic acid > 90 % connected with a relatively stable catalytic performance was obtained by HMF oxidation on a Pd/ZrO2/La2O3. A lactic acid yield of 75 % was obtained by GLY oxidation on a Pd-Ag/TiO2 which showed also a stable catalytic performance when the catalyst was recycled. The prepared catalysts were characterized by various methods before and after the oxidation reactions.