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Eleya,  Nadi Fakhry

Synthesis of Functionalized Quinolines, Flavones, Coumarins, Naphthoates and Phthalates by Site-Selective Suzuki-Miyaura Cross-Coupling Reactions

Rostock : Universität , 2012

https://doi.org/10.18453/rosdok_id00001028

http://purl.uni-rostock.de/rosdok/id00001028

Abstract:

This thesis includes regioselective palladium(0)-catalyzed Suzuki cross-coupling reactions of quinolines, flavones, coumarins, naphthaoates and phthalates. Suzuki cross-coupling reaction of 5,7-dibromo-8-(trifluoromethanesulfonyloxy)quinoline afforded arylated quinolines.The Suzuki reaction of the bis(triflates)of 5,7-dihydroxyflavone,4-methyl-5,7-dihydroxycoumarin,4-methyl-5,8-dihydroxycoumarin, ethyl 3,5-dihydroxy-2-naphthaoate and methyl 3,7-dihydroxy-2-naphthoate gave the corresponding arylated derivatives. The reaction of tetrabromophthalate with boronic acids gave tetraarylphthalates.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Maison,  Wolfgang  (Prof. Dr.)
Langer,  Peter  (Prof. Dr.)
Jahr der Abgabe:
2012
Jahr der Verteidigung:
2012
Sprache(n) :
Englisch
Schlagworte:
cross-coupling, Palladium, regioselectivity
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2012-0067-9
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001028
erstellt am:
2012-09-06
zuletzt geändert am:
2018-06-30
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