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Thiel,  Indre

Synthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactions

Rostock : Universität , 2014

https://doi.org/10.18453/rosdok_id00001292

http://purl.uni-rostock.de/rosdok/id00001292

Abstract:

This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Rosenthal,  Uwe  (Prof. Dr. rer. nat. habil.)
Tamm,  Matthias  (Prof. Dr.)
Jahr der Abgabe:
2013
Jahr der Verteidigung:
2013
Sprache(n) :
Englisch
Schlagworte:
catalysis, pyridines, heteroleptic compounds, Katalyse
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2014-0044-1
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001292
erstellt am:
2014-02-18
zuletzt geändert am:
2018-06-30
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