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Lisaj,  Mateusz

Laser control and spectroscopy of molecular vibrations and reaction dynamics

Rostock : Universität , 2015

https://doi.org/10.18453/rosdok_id00001582

http://purl.uni-rostock.de/rosdok/id00001582

Abstract:

The main subjects of this work are the ultrafast laser driven quantum dynamics of collective CO vibrations in a metal-dicarbonyl complex. The fundamental insights into the interactions responsible for bond dissociation are obtained by using shaped laser pulses to steer molecular quantum dynamics. Specifically, CpCo(CO)2 is studied on the basis of a four-dimensional reactive potential energy surface (PES). It is shown that two perpendicularly polarized IR laser pulses can be used to trigger an alternating localization of the vibration within one CO bond.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Kühn,  Oliver  (Prof. Dr.)
May,  Volkhard  (PD Dr. habil.)
Jahr der Abgabe:
2015
Jahr der Verteidigung:
2015
Sprache(n) :
Englisch
Schlagworte:
femtosecond IR pulses, metal-carbonyl complexes, alcoholysis reactions, bond breaking, transient localization, wave packet dynamics
DDC Klassifikation :
530 Physik
URN :
urn:nbn:de:gbv:28-diss2015-0132-4
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001582
erstellt am:
2015-08-05
zuletzt geändert am:
2018-06-30
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