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Gevorgyan,  Ashot

Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro group

Rostock : Universität , 2015

https://doi.org/10.18453/rosdok_id00001646

http://purl.uni-rostock.de/rosdok/id00001646

Abstract:

The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Langer,  Peter  (Prof. Dr.)
Wolfgang,  Maison  (Prof. Dr.)
Jahr der Abgabe:
2015
Jahr der Verteidigung:
2015
Sprache(n) :
Englisch
Schlagworte:
C-H activation, Pd, Ni, purine-like compounds, pyrazole, imidazole
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2015-0196-5
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001646
erstellt am:
2015-12-08
zuletzt geändert am:
2018-06-30
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