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Hackbarth,  Liisa

Tetracyanidoborates with triply charged rare earth metal cations and their optical properties

Rostock : Universität , 2015

https://doi.org/10.18453/rosdok_id00001648

http://purl.uni-rostock.de/rosdok/id00001648

Abstract:

A new group of tetracyanidoborates - tetracyanidoborates with trivalent rare earth metal cations - was synthesized. The rare earth tetracyanidoborates form isostructural groups, e.g. [LRE(H2O)5][B(CN)4]3•0.5 H2O, with LRE3+ = La, Ce, Pr, Nd, Sm, Eu, Gd and [HRE(H2O)7][B(CN)4]3 with HRE3+ = Tb, Dy, Ho, Er, Tm, Yb, Lu and Y. These tetracyanidoborates exhibit rare earth cation specific luminescence properties which are improved by the tetracyanidoborate anion. Therefore, the tetracyanidoborates with trivalent rare earth metal cations could have possible applications in phosphors.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Köckerling,  Martin  (Prof. Dr. rer. nat.)
Lochbrunner,  Stefan  (Prof. Dr. rer. nat.)
Jahr der Abgabe:
2015
Jahr der Verteidigung:
2015
Sprache(n) :
Englisch
Schlagworte:
counterion, isostructural groups, luminescence
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2015-0198-7
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001648
erstellt am:
2015-12-08
zuletzt geändert am:
2018-06-30
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