Vu,  Toan Van

Catalysis with porous MOFs  : structure-catalytic property-relationships in the hydroformylation of olefins over Rh supported metal-organic frameworks

Rostock : Universität , 2015

https://doi.org/10.18453/rosdok_id00001665

http://purl.uni-rostock.de/rosdok/id00001665

Abstract:

It deals with preparation, characterization, and catalytic testing of Rh supported catalysts based on MOFs using hydroformylation as a model reaction. The influence of the MOF support on the catalytic performance (Structure-Catalytic Property-Relationships) is emphasized. Different MOF structures and pore sizes were synthesized, Rh immobilized, characterized, and tested. Results show that single site catalysts are achieved. The catalytic performance is affected by the structure, texture, and porosity of the MOF support. The linker orientation is of importance leading to single-file diffusion.

Dissertation Open Access