zum Inhalt

 

AL-Ramadhani,  Omar Mowafaq Younis

Synthesis and characterization of new CN-based transition metal complexes

Rostock : Universität , 2017

https://doi.org/10.18453/rosdok_id00001837

http://purl.uni-rostock.de/rosdok/id00001837

Abstract:

In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Schulz,  Axel  (Prof. Dr.)
Rosenthal,  Uwe  (Prof. Dr.)
Jahr der Abgabe:
2016
Jahr der Verteidigung:
2016
Sprache(n) :
Englisch
Schlagworte:
tricyanophosphine, transition metal complexes, tetracyanopyrrolide, pseudohalogen, coordination polymers, Ionic liquids
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2017-0001-6
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001837
erstellt am:
2017-01-13
zuletzt geändert am:
2018-06-30
Volltext