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Vogt,  Lydia Katharina

Hydrogen generation from the chemical energy carrier methanol  : mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system

Rostock : Universität , 2017

https://doi.org/10.18453/rosdok_id00001922

http://purl.uni-rostock.de/rosdok/id00001922

Abstract:

This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable catalyst system based on the base metal manganese was implemented for the low-temperature dehydrogenation of methanol.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Beller,  Matthias  (Prof. Dr.)
Laurenczy,  Gabor  (Prof. Dr.)
Jahr der Abgabe:
2017
Jahr der Verteidigung:
2017
Sprache(n) :
Englisch
Schlagworte:
methanol reforming, homogeneous catalysis, pincer complex
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2017-0086-0
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00001922
erstellt am:
2017-06-28
zuletzt geändert am:
2018-06-30
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