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Pham,  Ngo Nghia

Palladium-catalyzed synthesis of pyrrole-, indole- and phenanthridine-fused polycyclic aromatic compounds from ortho-dihaloarenes

Rostock : Universität , 2018

https://doi.org/10.18453/rosdok_id00002047

http://purl.uni-rostock.de/rosdok/id00002047

Abstract:

Convenient palladium-catalyzed syntheses of polycyclic nitrogen heterocycles from ortho-dihaloarenes were developed. First, syntheses of pyrrole-fused derivatives via domino C-C/C-N coupling of ortho-dihaloarenes with imines were accomplished. Employment of ortho-dihaloarenes for sequential regioselective Suzuki reaction/double C-N coupling afforded corresponding indole-fused structures. Finally, syntheses of previously unexplored phenanthridine-fused architectures by regioselective Sonogashira reaction followed by domino or one-pot C-N coupling/hydroamination/C-H arylation were described.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Langer,  Peter  (Prof. Dr. Dr. h. c. mult.)
Schmidt,  Andreas  (apl. Prof. Dr. rer. nat. habil.)
Jahr der Abgabe:
2016
Jahr der Verteidigung:
2017
Sprache(n) :
Englisch
Schlagworte:
palladium-catalyzed, cross-coupling, domino reaction
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2018-0041-4
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00002047
erstellt am:
2018-03-23
zuletzt geändert am:
2018-06-30
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