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Jaime Trevin̂o,  Diego A.

Selective oxidation of C16 macrocyclic diene to epoxides and ketones

Rostock : Universität , 2017

https://doi.org/10.18453/rosdok_id00002353

http://purl.uni-rostock.de/rosdok/id00002353

In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Martin,  Andreas
Prüße,  Ulf
Sprache(n) :
Englisch
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-diss2018-0180-6
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00002353
erstellt am:
2018-12-06
zuletzt geändert am:
2018-12-06
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