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Woźniak,  Bartosz

Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate

Rostock : Universität , 2018

https://doi.org/10.18453/rosdok_id00002403

http://purl.uni-rostock.de/rosdok/id00002403

Abstract:

This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.

Dissertation Open Access


Einrichtung :
Mathematisch-Naturwissenschaftliche Fakultät
Gutachter :
Vries,  Johannes de
Barta,  Katalin
Sprache(n) :
Englisch
DDC Klassifikation :
540 Chemie
URN :
urn:nbn:de:gbv:28-rosdok_id00002403-7
Persistente URL:
http://purl.uni-rostock.de/rosdok/id00002403
erstellt am:
2019-02-13
zuletzt geändert am:
2019-02-13
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