10.18453/rosdok_id00000313
Karapetyan, Gnuni
Gnuni
Karapetyan
http://d-nb.info/gnd/135694264
null excursion into the chemistry of N- and C-glycosides of D-galacturonic acid
Universität Rostock
2008
540 Chemistry & allied sciences
2008
en
http://purl.uni-rostock.de/rosdok/id00000313
urn:nbn:de:gbv:28-diss2008-0045-2
In the present work the synthesis of D-galacturonic acid N- and C-glycosides is described. Several protecting strategies were investigated for the synthesis and structural characterization of 1-azido and C-allyl galacturonates as suitable building blocks. Derivatization of azido and C-allyl moieties is described resulting in biotinylated compounds which can be used for the synthesis of labelled pectin fragments. Such biotinylated fragments are useful tools in biochemical assays.