mycoreobjectrosdok_disshab_0000000157rosdok_disshab_0000000157rosdokdisshabrosdok_derivate_00000037182023-08-08T10:00:36.491Z2009-03-03T12:07:07.656Zadministratorpublished1rosdok_derivate_0000003718truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00000409592878198MODS updated during RosDok migration in June 2021DissertationHochschulschrift137495889DirkHollmann1977-VerfasserInautNew applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesenProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.Jonathan M. J.WilliamsAkademischeR BetreuerIndgsLutzAckermannAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000409http://purl.uni-rostock.de/rosdok/id00000409urn:nbn:de:gbv:28-diss2009-0012-1540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2008monographic20082008Universitätsbibliothek RostockRostock20092009This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed.RutheniumAminationAlkylationUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000409doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/New applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesNew applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesgnd:137495889gnd:2147083-2gnd:137495889gnd:2147083-2rosdok_disshab_0000000157-d1085060e39gnd:137495889Dirk HollmannDirk Hollmannrosdok_disshab_0000000157-d1085060e60Prof. Dr. Matthias BellerProf. Dr. Matthias Bellerrosdok_disshab_0000000157-d1085060e72Prof. Dr. Jonathan M. J. WilliamsProf. Dr. Jonathan M. J. Williamsrosdok_disshab_0000000157-d1085060e84Lutz AckermannLutz Ackermannrosdok_disshab_0000000157-d1085060e95gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannProf. Dr. Matthias BellerProf. Dr. Jonathan M. J. WilliamsLutz AckermannUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannProf. Dr. Matthias BellerProf. Dr. Jonathan M. J. WilliamsLutz AckermannUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000409http://purl.uni-rostock.de/rosdok/id00000409urn:nbn:de:gbv:28-diss2009-0012-1RutheniumAminationAlkylationThis cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed.20082008epub.dissertation1 Dissertation_Hollmann_2009.pdf 2806376 e5e44e178420f5d11c8fbd6f36d0b16e rosdok/id00000409592878198MODS updated during RosDok migration in June 2021DissertationHochschulschrift137495889DirkHollmann1977-VerfasserInautNew applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesenProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.Jonathan M. J.WilliamsAkademischeR BetreuerIndgsLutzAckermannAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000409http://purl.uni-rostock.de/rosdok/id00000409urn:nbn:de:gbv:28-diss2009-0012-1540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2008monographic20082008Universitätsbibliothek RostockRostock20092009This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. 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J. WilliamsProf. Dr. Jonathan M. J. Williamsrosdok_disshab_0000000157-d1085060e84Lutz AckermannLutz Ackermannrosdok_disshab_0000000157-d1085060e95gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannProf. Dr. Matthias BellerProf. Dr. Jonathan M. J. WilliamsLutz AckermannUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannProf. Dr. Matthias BellerProf. Dr. Jonathan M. J. WilliamsLutz AckermannUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDirk HollmannRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000409http://purl.uni-rostock.de/rosdok/id00000409urn:nbn:de:gbv:28-diss2009-0012-1RutheniumAminationAlkylationThis cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed.20082008[xslt]Saxonrosdok/id00000409https://purl.uni-rostock.de/rosdok/id0000040959287819810.18453/rosdok_id00000409urn:nbn:de:gbv:28-diss2009-0012-1Dirk HollmannHollmann DirkNew applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesDissertationdoctoral thesisUniversität Rostock, 2008This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was…Dirk HollmannNew applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studiesUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000409137495889DirkHollmann1977-VerfasserInautProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.Jonathan M. J.WilliamsAkademischeR BetreuerIndgsLutzAckermannAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00000409[purl]http://purl.uni-rostock.de/rosdok/id00000409[urn]urn:nbn:de:gbv:28-diss2009-0012-1open_access20082008epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published