mycoreobjectrosdok_disshab_0000000285rosdok_disshab_0000000285rosdokdisshabrosdok_derivate_00000039572023-08-08T10:01:07.486Z2009-07-30T12:08:36.592Zadministratorpublished1rosdok_derivate_0000003957truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00000523605638799MODS updated during RosDok migration in June 2021DissertationHochschulschrift138811040InamIqbal1978-VerfasserInautSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateenProf. Dr.PeterLangerAkademischeR BetreuerIndgsProf. Dr.MatthiasBellerAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000523http://purl.uni-rostock.de/rosdok/id00000523urn:nbn:de:gbv:28-diss2009-0141-8540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2009monographic20092009Universitätsbibliothek RostockRostock20092009The work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael′ reactions of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes with 1,1-diacylcyclopropanes. In the second chapter, a regioselective synthesis of 2-(arylthio)benzoates by the first [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-alkoxy-2-en-1-ones is reported. In the third chapter, the synthesis of 5-arylthio-3-hydroxyphthalates by the first [4+2] cycloadditions of 3-arylthio-1-silyloxy-1,3-butadienes with dimethyl acetylenedicarboxylate is reported.Arylthiobenzoates[3+3] Cyclization[4+2] CycloadditionUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000523doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Synthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylategnd:138811040gnd:2147083-2gnd:138811040gnd:2147083-2rosdok_disshab_0000000285-d221814e39gnd:138811040Inam IqbalInam Iqbalrosdok_disshab_0000000285-d221814e60Prof. Dr. Peter LangerProf. Dr. Peter Langerrosdok_disshab_0000000285-d221814e72Prof. Dr. Matthias BellerProf. Dr. Matthias Bellerrosdok_disshab_0000000285-d221814e84gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalProf. Dr. Peter LangerProf. Dr. Matthias BellerUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalProf. Dr. Peter LangerProf. Dr. Matthias BellerUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000523http://purl.uni-rostock.de/rosdok/id00000523urn:nbn:de:gbv:28-diss2009-0141-8Arylthiobenzoates[3+3] Cyclization[4+2] CycloadditionThe work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael′ reactions of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes with 1,1-diacylcyclopropanes. In the second chapter, a regioselective synthesis of 2-(arylthio)benzoates by the first [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-alkoxy-2-en-1-ones is reported. In the third chapter, the synthesis of 5-arylthio-3-hydroxyphthalates by the first [4+2] cycloadditions of 3-arylthio-1-silyloxy-1,3-butadienes with dimethyl acetylenedicarboxylate is reported.20092009epub.dissertation1 Dissertation_Iqbal_2009.pdf 2502523 847f60ff9e323beb8cc4e806e9961aa4 rosdok/id00000523605638799MODS updated during RosDok migration in June 2021DissertationHochschulschrift138811040InamIqbal1978-VerfasserInautSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateenProf. Dr.PeterLangerAkademischeR BetreuerIndgsProf. Dr.MatthiasBellerAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000523http://purl.uni-rostock.de/rosdok/id00000523urn:nbn:de:gbv:28-diss2009-0141-8540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2009monographic20092009Universitätsbibliothek RostockRostock20092009The work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael′ reactions of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes with 1,1-diacylcyclopropanes. In the second chapter, a regioselective synthesis of 2-(arylthio)benzoates by the first [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-alkoxy-2-en-1-ones is reported. In the third chapter, the synthesis of 5-arylthio-3-hydroxyphthalates by the first [4+2] cycloadditions of 3-arylthio-1-silyloxy-1,3-butadienes with dimethyl acetylenedicarboxylate is reported.Arylthiobenzoates[3+3] Cyclization[4+2] CycloadditionUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000523 2009-07-30T12:08:36.592Z 2023-08-08T10:01:07.486Z 2023-08-18T10:01:07.491Z {"identifier":"rosdok/id00000523","type":"local_id","additional":"","service":"MCRLocalID","created":"2018-06-30T12:39:47.059Z"} {"identifier":"http://purl.uni-rostock.de/rosdok/id00000523","type":"purl","additional":"","service":"RosDokPURL","created":"2018-06-30T12:39:47.194Z","registered":"2018-06-30T12:39:47.194Z"} {"identifier":"10.18453/rosdok_id00000523","type":"doi","additional":"","service":"RosDokDOI","created":"2018-06-30T12:39:48.490Z","registered":"2018-06-30T12:39:48.490Z"} {"identifier":"urn:nbn:de:gbv:28-diss2009-0141-8","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2018-06-30T12:39:47.064Z","registered":"2009-07-31T02:19:52.953Z"} administratorfulltextfile/rosdok_disshab_0000000285/rosdok_derivate_0000003957/Dissertation_Iqbal_2009.pdfSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylategnd:138811040gnd:2147083-2gnd:138811040gnd:2147083-2rosdok_disshab_0000000285-d221814e39gnd:138811040Inam IqbalInam Iqbalrosdok_disshab_0000000285-d221814e60Prof. Dr. Peter LangerProf. Dr. Peter Langerrosdok_disshab_0000000285-d221814e72Prof. Dr. Matthias BellerProf. Dr. Matthias Bellerrosdok_disshab_0000000285-d221814e84gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalProf. Dr. Peter LangerProf. Dr. Matthias BellerUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalProf. Dr. Peter LangerProf. Dr. Matthias BellerUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätInam IqbalRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000523http://purl.uni-rostock.de/rosdok/id00000523urn:nbn:de:gbv:28-diss2009-0141-8Arylthiobenzoates[3+3] Cyclization[4+2] CycloadditionThe work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael′ reactions of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes with 1,1-diacylcyclopropanes. In the second chapter, a regioselective synthesis of 2-(arylthio)benzoates by the first [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-alkoxy-2-en-1-ones is reported. In the third chapter, the synthesis of 5-arylthio-3-hydroxyphthalates by the first [4+2] cycloadditions of 3-arylthio-1-silyloxy-1,3-butadienes with dimethyl acetylenedicarboxylate is reported.20092009[xslt]Saxonrosdok/id00000523https://purl.uni-rostock.de/rosdok/id0000052360563879910.18453/rosdok_id00000523urn:nbn:de:gbv:28-diss2009-0141-8Inam IqbalIqbal InamSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateDissertationdoctoral thesisUniversität Rostock, 2009The work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael′ reactions of…Inam IqbalSynthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylateUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000523138811040InamIqbal1978-VerfasserInautProf. Dr.PeterLangerAkademischeR BetreuerIndgsProf. Dr.MatthiasBellerAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00000523[purl]http://purl.uni-rostock.de/rosdok/id00000523[urn]urn:nbn:de:gbv:28-diss2009-0141-8open_access20092009epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published