mycoreobjectrosdok_disshab_0000000700rosdok_disshab_0000000700rosdokdisshabrosdok_derivate_00000046832023-08-08T10:02:50.905Z2011-08-10T16:46:00.092Zadministratorpublished1rosdok_derivate_0000004683truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id0000089766775279XMODS updated during RosDok migration in June 2021DissertationHochschulschrift1014975603ShaolinZhou1976-VerfasserInautDevelopment of New Homogeneous (Enantioselective)Hydrogenation Catalysts Based on Bio‐relevant MetalsenProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.AminBörnerAkademischeR BetreuerIndgsProf. Dr.ChristophSchneiderAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000897http://purl.uni-rostock.de/rosdok/id00000897urn:nbn:de:gbv:28-diss2011-0127-7540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2011monographic20112011Universitätsbibliothek RostockRostock20112011This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. 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Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Development of New Homogeneous (Enantioselective)Hydrogenation Catalysts Based on Bio‐relevant MetalsDevelopment of New Homogeneous (Enantioselective)Hydrogenation Catalysts Based on Bio‐relevant Metalsgnd:1014975603gnd:2147083-2gnd:1014975603gnd:2147083-2rosdok_disshab_0000000700-d1541294e39gnd:1014975603Shaolin ZhouShaolin Zhourosdok_disshab_0000000700-d1541294e61Prof. Dr. Matthias BellerProf. Dr. Matthias Bellerrosdok_disshab_0000000700-d1541294e73Prof. Dr. Amin BörnerProf. Dr. Amin Börnerrosdok_disshab_0000000700-d1541294e85Prof. Dr. Christoph SchneiderProf. Dr. Christoph Schneiderrosdok_disshab_0000000700-d1541294e98gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätShaolin ZhouProf. Dr. Matthias BellerProf. Dr. Amin BörnerProf. Dr. Christoph SchneiderUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätShaolin ZhouProf. Dr. Matthias BellerProf. Dr. Amin BörnerProf. Dr. Christoph SchneiderUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätShaolin ZhouRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000897http://purl.uni-rostock.de/rosdok/id00000897urn:nbn:de:gbv:28-diss2011-0127-7catalysisreductioniminesamidesironThis thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.20112011epub.dissertation1 Dissertation_Zhou_2011.pdf 921841 507cd318d696d89d82c0878989e98c98 rosdok/id0000089766775279XMODS updated during RosDok migration in June 2021DissertationHochschulschrift1014975603ShaolinZhou1976-VerfasserInautDevelopment of New Homogeneous (Enantioselective)Hydrogenation Catalysts Based on Bio‐relevant MetalsenProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.AminBörnerAkademischeR BetreuerIndgsProf. Dr.ChristophSchneiderAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000897http://purl.uni-rostock.de/rosdok/id00000897urn:nbn:de:gbv:28-diss2011-0127-7540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2011monographic20112011Universitätsbibliothek RostockRostock20112011This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. 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An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.20112011[xslt]Saxonrosdok/id00000897https://purl.uni-rostock.de/rosdok/id0000089766775279X10.18453/rosdok_id00000897urn:nbn:de:gbv:28-diss2011-0127-7Shaolin ZhouZhou ShaolinDevelopment of New Homogeneous (Enantioselective) : Hydrogenation Catalysts Based on Bio‐relevant MetalsDissertationdoctoral thesisUniversität Rostock, 2011This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of…Shaolin ZhouDevelopment of New Homogeneous (Enantioselective)Hydrogenation Catalysts Based on Bio‐relevant MetalsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000008971014975603ShaolinZhou1976-VerfasserInautProf. Dr.MatthiasBellerAkademischeR BetreuerIndgsProf. Dr.AminBörnerAkademischeR BetreuerIndgsProf. Dr.ChristophSchneiderAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00000897[purl]http://purl.uni-rostock.de/rosdok/id00000897[urn]urn:nbn:de:gbv:28-diss2011-0127-7open_access20112011epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published