mycoreobjectrosdok_disshab_0000000771rosdok_disshab_0000000771rosdokdisshabrosdok_derivate_00000047732023-08-08T10:03:09.923Z2011-12-21T09:26:13.275Zadministratorpublished1rosdok_derivate_0000004773truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00000962684227215MODS updated during RosDok migration in June 2021DissertationHochschulschrift1018502777NeetikaMadaan1984-VerfasserInautGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and RegenerationenProf. Dr.AngelikaBrücknerAkademischeR BetreuerIndgsDr. habil.AndreasMartinAkademischeR BetreuerIndgsProf. Dr.ErhardKemnitzAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000962http://purl.uni-rostock.de/rosdok/id00000962urn:nbn:de:gbv:28-diss2011-0198-7540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2011monographic20112011Universitätsbibliothek RostockRostock20112011Acetoxylation of toluene (Tol) to Benzyl acetate (BA) takes place in the presence of acetic acid and O2. Pd based catalysts are known to be active for this system. In this study, Pd-Sb/TiO2 catalyst pre-treated in helium showed 54 % of toluene conversion and 89 % of BA selectivity with stability of 25 hours. The deactivated catalysts were effectively regenerated at 300 °C/2h/air. Additionally pressure showed strong influence on the performance. Acetoxylation with other substituted toluenes with varying electron withdrawing and donating group were also successfully performed.toluenePd-valancestabilityhigh selectivityUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000962doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Gas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and RegenerationGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and Regenerationgnd:1018502777gnd:2147083-2gnd:1018502777gnd:2147083-2rosdok_disshab_0000000771-d2100177e39gnd:1018502777Neetika MadaanNeetika Madaanrosdok_disshab_0000000771-d2100177e61Prof. Dr. Angelika BrücknerProf. Dr. Angelika Brücknerrosdok_disshab_0000000771-d2100177e73Dr. habil. Andreas MartinDr. habil. Andreas Martinrosdok_disshab_0000000771-d2100177e85Prof. Dr. Erhard KemnitzProf. Dr. Erhard Kemnitzrosdok_disshab_0000000771-d2100177e98gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanProf. Dr. Angelika BrücknerDr. habil. Andreas MartinProf. Dr. Erhard KemnitzUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanProf. Dr. Angelika BrücknerDr. habil. Andreas MartinProf. Dr. Erhard KemnitzUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000962http://purl.uni-rostock.de/rosdok/id00000962urn:nbn:de:gbv:28-diss2011-0198-7toluenePd-valancestabilityhigh selectivityAcetoxylation of toluene (Tol) to Benzyl acetate (BA) takes place in the presence of acetic acid and O2. Pd based catalysts are known to be active for this system. In this study, Pd-Sb/TiO2 catalyst pre-treated in helium showed 54 % of toluene conversion and 89 % of BA selectivity with stability of 25 hours. The deactivated catalysts were effectively regenerated at 300 °C/2h/air. Additionally pressure showed strong influence on the performance. Acetoxylation with other substituted toluenes with varying electron withdrawing and donating group were also successfully performed.20112011epub.dissertation1 Dissertation_Madaan_2011.pdf 12702184 9cab7aa9adb9605bbc2a17dffec5e7ef rosdok/id00000962684227215MODS updated during RosDok migration in June 2021DissertationHochschulschrift1018502777NeetikaMadaan1984-VerfasserInautGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and RegenerationenProf. Dr.AngelikaBrücknerAkademischeR BetreuerIndgsDr. habil.AndreasMartinAkademischeR BetreuerIndgsProf. Dr.ErhardKemnitzAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00000962http://purl.uni-rostock.de/rosdok/id00000962urn:nbn:de:gbv:28-diss2011-0198-7540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2011monographic20112011Universitätsbibliothek RostockRostock20112011Acetoxylation of toluene (Tol) to Benzyl acetate (BA) takes place in the presence of acetic acid and O2. Pd based catalysts are known to be active for this system. In this study, Pd-Sb/TiO2 catalyst pre-treated in helium showed 54 % of toluene conversion and 89 % of BA selectivity with stability of 25 hours. The deactivated catalysts were effectively regenerated at 300 °C/2h/air. Additionally pressure showed strong influence on the performance. Acetoxylation with other substituted toluenes with varying electron withdrawing and donating group were also successfully performed.toluenePd-valancestabilityhigh selectivityUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00000962 2011-12-21T09:26:13.275Z 2023-08-08T10:03:09.923Z 2023-08-18T10:03:09.928Z {"identifier":"rosdok/id00000962","type":"local_id","additional":"","service":"MCRLocalID","created":"2018-06-30T12:55:25.533Z"} {"identifier":"http://purl.uni-rostock.de/rosdok/id00000962","type":"purl","additional":"","service":"RosDokPURL","created":"2018-06-30T12:55:25.726Z","registered":"2018-06-30T12:55:25.726Z"} {"identifier":"10.18453/rosdok_id00000962","type":"doi","additional":"","service":"RosDokDOI","created":"2018-06-30T12:55:27.014Z","registered":"2018-06-30T12:55:27.014Z"} {"identifier":"urn:nbn:de:gbv:28-diss2011-0198-7","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2018-06-30T12:55:25.538Z","registered":"2012-01-27T03:02:34.023Z"} administratorfulltextfile/rosdok_disshab_0000000771/rosdok_derivate_0000004773/Dissertation_Madaan_2011.pdfGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and RegenerationGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and Regenerationgnd:1018502777gnd:2147083-2gnd:1018502777gnd:2147083-2rosdok_disshab_0000000771-d2100177e39gnd:1018502777Neetika MadaanNeetika Madaanrosdok_disshab_0000000771-d2100177e61Prof. Dr. Angelika BrücknerProf. Dr. Angelika Brücknerrosdok_disshab_0000000771-d2100177e73Dr. habil. Andreas MartinDr. habil. Andreas Martinrosdok_disshab_0000000771-d2100177e85Prof. Dr. Erhard KemnitzProf. Dr. Erhard Kemnitzrosdok_disshab_0000000771-d2100177e98gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanProf. Dr. Angelika BrücknerDr. habil. Andreas MartinProf. Dr. Erhard KemnitzUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanProf. Dr. Angelika BrücknerDr. habil. Andreas MartinProf. Dr. Erhard KemnitzUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätNeetika MadaanRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00000962http://purl.uni-rostock.de/rosdok/id00000962urn:nbn:de:gbv:28-diss2011-0198-7toluenePd-valancestabilityhigh selectivityAcetoxylation of toluene (Tol) to Benzyl acetate (BA) takes place in the presence of acetic acid and O2. Pd based catalysts are known to be active for this system. In this study, Pd-Sb/TiO2 catalyst pre-treated in helium showed 54 % of toluene conversion and 89 % of BA selectivity with stability of 25 hours. The deactivated catalysts were effectively regenerated at 300 °C/2h/air. Additionally pressure showed strong influence on the performance. Acetoxylation with other substituted toluenes with varying electron withdrawing and donating group were also successfully performed.20112011[xslt]Saxonrosdok/id00000962https://purl.uni-rostock.de/rosdok/id0000096268422721510.18453/rosdok_id00000962urn:nbn:de:gbv:28-diss2011-0198-7Neetika MadaanMadaan NeetikaGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 Catalysts : Activation, Steady-State Operation, Deactivation and RegenerationDissertationdoctoral thesisUniversität Rostock, 2011Acetoxylation of toluene (Tol) to Benzyl acetate (BA) takes place in the presence of acetic acid and O2. Pd based catalysts are known to be active for this system. In this study, Pd-Sb/TiO2 catalyst pre-treated in helium showed 54 % of toluene conversion and 89 % of BA selectivity with stability of…Neetika MadaanGas Phase Acetoxylation of Methyl Aromatics to their Corresponding Esters over PdSb/TiO2 CatalystsActivation, Steady-State Operation, Deactivation and RegenerationUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000009621018502777NeetikaMadaan1984-VerfasserInautProf. Dr.AngelikaBrücknerAkademischeR BetreuerIndgsDr. habil.AndreasMartinAkademischeR BetreuerIndgsProf. Dr.ErhardKemnitzAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00000962[purl]http://purl.uni-rostock.de/rosdok/id00000962[urn]urn:nbn:de:gbv:28-diss2011-0198-7open_access20112011epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published