Synthesis of Functionalized Benzofurans, Diaryl-Substituted 1,2,3,4-Tetrahydro-9,10-Anthracen-1-ones, 5,10-Diaryl-11Hbenzo[b]fluoren-11-ones, Benzothieno[3,2-b]quinolines, Thieno[3,2-b]pyrroles, Benzofuro[3,2-b]quinolines, and Furo[3,2-b]quinolines by Regioselective Palladium(0)-Catalyzed Cross-Coupling and Domino C-N Coupling/Annulation Reactions

10.18453/rosdok_id00000983 Salman, Ghazwan Ali Ghazwan Ali Salman http://d-nb.info/gnd/1020214058 Synthesis of Functionalized Benzofurans, Diaryl-Substituted 1,2,3,4-Tetrahydro-9,10-Anthracen-1-ones, 5,10-Diaryl-11Hbenzo[b]fluoren-11-ones, Benzothieno[3,2-b]quinolines, Thieno[3,2-b]pyrroles, Benzofuro[3,2-b]quinolines, and Furo[3,2-b]quinolines by Regioselective Palladium(0)-Catalyzed Cross-Coupling and Domino C-N Coupling/Annulation Reactions Universität Rostock 2011 540 Chemistry & allied sciences 2011 en http://purl.uni-rostock.de/rosdok/id00000983 urn:nbn:de:gbv:28-diss2012-0018-7 The palladium(0)-catalyzed Heck cross-coupling and suzuki-Miyaura reactions of 2,3-dibromo-5-(ethoxycarbonyl)-furan, bis(triflate) of 1,2,3,4-tetrahydro-9,10-dihydroxyanthracen-1-one, and 5,10-dihydroxy-11H-benzo[b]fluoren-11-one, afforded different diarylation compounds. The palladium catalyzed reaction of 2-alkynyl-3-bromothiophenes, 2-alkynyl-3-bromobenzothiophene, 2-alkynyl-3-bromofurans, and 2-alkynyl-3-bromobenzofurans with anilines afforded thienopyrroles, benzothienoquinolines, fuoroquinoline, and benzofuoroquinolines, respectively by a domino C-N coupling / annulations and hydroamination reactions.