mycoreobjectrosdok_disshab_0000001023rosdok_disshab_0000001023rosdokdisshabrosdok_derivate_00000051402023-08-08T10:04:15.568Z2013-08-22T10:08:36.242Zadministratorpublished1rosdok_derivate_0000005140truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00001202766278522MODS updated during RosDok migration in June 2021DissertationHochschulschrift1038176794QiquanLuo1984-VerfasserInautTheoretical study of formic acid dehydrogenation and full hydrogenation of acroleinen131449311PD Dr.HaijunJiaoLeibniz-Institut für Katalyse e. V., Universität RostockAkademischeR BetreuerIndgs136437524Prof. Dr.RalfLudwigInstitut für Chemie, Universität RostockAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001202http://purl.uni-rostock.de/rosdok/id00001202urn:nbn:de:gbv:28-diss2013-0115-0540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2013monographic20132013Universitätsbibliothek RostockRostock20132013This dissertation focused mainly on theoretical study of formic acid (HCOOH) decomposition on the Ni(111), Pd(111), Ni(211), Pd(211), Pt(211) and Mo2C(101) surfaces, since formic acid has been considered as one of potential materials in hydrogen storage and generation. The formate route plays the dominating role in formic acid decomposition; and the rate-determining step is the dissociation of formate into surface CO2 and H. 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V., Universität RostockAkademischeR BetreuerIndgs136437524Prof. Dr.RalfLudwigInstitut für Chemie, Universität RostockAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001202http://purl.uni-rostock.de/rosdok/id00001202urn:nbn:de:gbv:28-diss2013-0115-0540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2013monographic20132013Universitätsbibliothek RostockRostock20132013This dissertation focused mainly on theoretical study of formic acid (HCOOH) decomposition on the Ni(111), Pd(111), Ni(211), Pd(211), Pt(211) and Mo2C(101) surfaces, since formic acid has been considered as one of potential materials in hydrogen storage and generation. 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The formate route plays the dominating role in formic acid decomposition; and the rate-determining step is the dissociation of formate into surface CO2 and H. In addition, the Ni(111) surface was also employed to investigate the mechanism of full acrolein hydrogenation.20132013[xslt]Saxonrosdok/id00001202https://purl.uni-rostock.de/rosdok/id0000120276627852210.18453/rosdok_id00001202urn:nbn:de:gbv:28-diss2013-0115-0Qiquan LuoLuo QiquanTheoretical study of formic acid dehydrogenation and full hydrogenation of acroleinDissertationdoctoral thesisUniversität Rostock, 2013This dissertation focused mainly on theoretical study of formic acid (HCOOH) decomposition on the Ni(111), Pd(111), Ni(211), Pd(211), Pt(211) and Mo2C(101) surfaces, since formic acid has been considered as one of potential materials in hydrogen storage and generation. The formate route plays the…Qiquan LuoTheoretical study of formic acid dehydrogenation and full hydrogenation of acroleinUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000012021038176794QiquanLuo1984-VerfasserInaut131449311PD Dr.HaijunJiaoLeibniz-Institut für Katalyse e. V., Universität RostockAkademischeR BetreuerIndgs136437524Prof. Dr.RalfLudwigInstitut für Chemie, Universität RostockAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00001202[purl]http://purl.uni-rostock.de/rosdok/id00001202[urn]urn:nbn:de:gbv:28-diss2013-0115-0open_access20132013epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published