mycoreobjectrosdok_disshab_0000001113rosdok_disshab_0000001113rosdokdisshabrosdok_derivate_00000052522023-08-08T10:04:39.971Z2014-02-18T09:59:43.924Zadministratorpublished1rosdok_derivate_0000005252truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00001292779460162MODS updated during RosDok migration in June 2021DissertationHochschulschrift1047534681IndreThiel1987-VerfasserInautSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsen14076657XProf. Dr. rer. nat. habil.UweRosenthalUniversität Rostock, Leibniz-Institut für Katalyse e.V.AkademischeR BetreuerIndgsProf. Dr.MatthiasTammTechnische Universität Braunschweig, Institut für Anorganische und Analytische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001292http://purl.uni-rostock.de/rosdok/id00001292urn:nbn:de:gbv:28-diss2014-0044-1540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2014monographic20132014Universitätsbibliothek RostockRostock20142014This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.catalysispyridinesheteroleptic compoundsKatalyseUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00001292doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Synthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsgnd:1047534681gnd:14076657Xgnd:2147083-2gnd:1047534681gnd:14076657Xgnd:2147083-2rosdok_disshab_0000001113-d1188730e39gnd:1047534681Indre ThielIndre Thielrosdok_disshab_0000001113-d1188730e60gnd:14076657XProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. rer. nat. habil. Uwe Rosenthalrosdok_disshab_0000001113-d1188730e75Prof. Dr. Matthias TammProf. Dr. Matthias Tammrosdok_disshab_0000001113-d1188730e88gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. Matthias TammUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. Matthias TammUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00001292http://purl.uni-rostock.de/rosdok/id00001292urn:nbn:de:gbv:28-diss2014-0044-1catalysispyridinesheteroleptic compoundsKatalyseThis thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.20142014epub.dissertation1 Dissertation_Thiel_2014.pdf 5672108 3d6fcb7b01de18f99e7a63c3e05eacd2 rosdok/id00001292779460162MODS updated during RosDok migration in June 2021DissertationHochschulschrift1047534681IndreThiel1987-VerfasserInautSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsen14076657XProf. Dr. rer. nat. habil.UweRosenthalUniversität Rostock, Leibniz-Institut für Katalyse e.V.AkademischeR BetreuerIndgsProf. Dr.MatthiasTammTechnische Universität Braunschweig, Institut für Anorganische und Analytische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001292http://purl.uni-rostock.de/rosdok/id00001292urn:nbn:de:gbv:28-diss2014-0044-1540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2014monographic20132014Universitätsbibliothek RostockRostock20142014This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.catalysispyridinesheteroleptic compoundsKatalyseUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00001292 2014-02-18T09:59:43.924Z 2023-08-08T10:04:39.971Z 2023-08-18T10:04:39.975Z {"identifier":"rosdok/id00001292","type":"local_id","additional":"","service":"MCRLocalID","created":"2018-06-30T13:07:20.515Z"} {"identifier":"http://purl.uni-rostock.de/rosdok/id00001292","type":"purl","additional":"","service":"RosDokPURL","created":"2018-06-30T13:07:20.699Z","registered":"2018-06-30T13:07:20.699Z"} {"identifier":"10.18453/rosdok_id00001292","type":"doi","additional":"","service":"RosDokDOI","created":"2018-06-30T13:07:22.075Z","registered":"2018-06-30T13:07:22.075Z"} {"identifier":"urn:nbn:de:gbv:28-diss2014-0044-1","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2018-06-30T13:07:20.521Z","registered":"2014-02-28T03:02:47.457Z"} administratorfulltextfile/rosdok_disshab_0000001113/rosdok_derivate_0000005252/Dissertation_Thiel_2014.pdfSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsgnd:1047534681gnd:14076657Xgnd:2147083-2gnd:1047534681gnd:14076657Xgnd:2147083-2rosdok_disshab_0000001113-d1188730e39gnd:1047534681Indre ThielIndre Thielrosdok_disshab_0000001113-d1188730e60gnd:14076657XProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. rer. nat. habil. Uwe Rosenthalrosdok_disshab_0000001113-d1188730e75Prof. Dr. Matthias TammProf. Dr. Matthias Tammrosdok_disshab_0000001113-d1188730e88gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. Matthias TammUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielProf. Dr. rer. nat. habil. Uwe RosenthalProf. Dr. Matthias TammUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätIndre ThielRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00001292http://purl.uni-rostock.de/rosdok/id00001292urn:nbn:de:gbv:28-diss2014-0044-1catalysispyridinesheteroleptic compoundsKatalyseThis thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.20142014[xslt]Saxonrosdok/id00001292https://purl.uni-rostock.de/rosdok/id0000129277946016210.18453/rosdok_id00001292urn:nbn:de:gbv:28-diss2014-0044-1Indre ThielThiel IndreSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsDissertationdoctoral thesisUniversität Rostock, 2014This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic…Indre ThielSynthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactionsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000012921047534681IndreThiel1987-VerfasserInaut14076657XProf. Dr. rer. nat. habil.UweRosenthalUniversität Rostock, Leibniz-Institut für Katalyse e.V.AkademischeR BetreuerIndgsProf. Dr.MatthiasTammTechnische Universität Braunschweig, Institut für Anorganische und Analytische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00001292[purl]http://purl.uni-rostock.de/rosdok/id00001292[urn]urn:nbn:de:gbv:28-diss2014-0044-1open_access20142014epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published