mycoreobjectrosdok_disshab_0000001297rosdok_disshab_0000001297rosdokdisshabrosdok_derivate_00000238142023-08-08T10:05:37.105Z2015-02-10T14:06:21.094ZadministratoreditorDpublished1rosdok_derivate_0000023814truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00001476817979794MODS updated during RosDok migration in June 2021DissertationHochschulschrift1064972349LutzDomke1984-VerfasserInautAsymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsenProf. Dr.ArminBörnerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MontserratDiéguezUniversitat Rovira í Virgili, Tarragona, Spanien, Departament de Quimica Fisica í InorganicaAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001476http://purl.uni-rostock.de/rosdok/id00001476urn:nbn:de:gbv:28-diss2015-0026-6540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2015monographic20142015Universitätsbibliothek RostockRostock20152015Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.enantioselective synthesishomogeneous catalysisasymmetrische Hydrierungasymmetrische HydroformylierungUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00001476doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Asymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsAsymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsgnd:1064972349gnd:2147083-2gnd:1064972349gnd:2147083-2rosdok_disshab_0000001297-d812466e39gnd:1064972349Lutz DomkeLutz Domkerosdok_disshab_0000001297-d812466e60Prof. Dr. Armin BörnerProf. Dr. Armin Börnerrosdok_disshab_0000001297-d812466e73Prof. Dr. Montserrat DiéguezProf. Dr. Montserrat Diéguezrosdok_disshab_0000001297-d812466e86gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätLutz DomkeProf. Dr. Armin BörnerProf. Dr. Montserrat DiéguezUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätLutz DomkeProf. Dr. Armin BörnerProf. Dr. Montserrat DiéguezUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätLutz DomkeRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00001476http://purl.uni-rostock.de/rosdok/id00001476urn:nbn:de:gbv:28-diss2015-0026-6enantioselective synthesishomogeneous catalysisasymmetrische Hydrierungasymmetrische HydroformylierungAsymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.20152015epub.dissertation1 Dissertation_Domke_2015.pdf 7509392 d69590b401feea9ed9af023a36c1d214 rosdok/id00001476817979794MODS updated during RosDok migration in June 2021DissertationHochschulschrift1064972349LutzDomke1984-VerfasserInautAsymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsenProf. Dr.ArminBörnerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MontserratDiéguezUniversitat Rovira í Virgili, Tarragona, Spanien, Departament de Quimica Fisica í InorganicaAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001476http://purl.uni-rostock.de/rosdok/id00001476urn:nbn:de:gbv:28-diss2015-0026-6540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2015monographic20142015Universitätsbibliothek RostockRostock20152015Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. 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Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.20152015[xslt]Saxonrosdok/id00001476https://purl.uni-rostock.de/rosdok/id0000147681797979410.18453/rosdok_id00001476urn:nbn:de:gbv:28-diss2015-0026-6Lutz DomkeDomke LutzAsymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsDissertationdoctoral thesisUniversität Rostock, 2015Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high…Lutz DomkeAsymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefinsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000014761064972349LutzDomke1984-VerfasserInautProf. Dr.ArminBörnerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MontserratDiéguezUniversitat Rovira í Virgili, Tarragona, Spanien, Departament de Quimica Fisica í InorganicaAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00001476[purl]http://purl.uni-rostock.de/rosdok/id00001476[urn]urn:nbn:de:gbv:28-diss2015-0026-6open_access20152015epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published