mycoreobjectrosdok_disshab_0000001467rosdok_disshab_0000001467rosdokdisshabrosdok_derivate_00000327972023-08-08T10:06:29.279Z2015-12-08T08:26:31.364ZadministratoreditorDpublished1rosdok_derivate_0000032797truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00001646842372687MODS updated during RosDok migration in June 2021DissertationHochschulschrift1079688854AshotGevorgyan1989-VerfasserInautExploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupen132314614Prof. Dr.PeterLangerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MaisonWolfgangUniversität Hamburg, Fachbereich Chemie, Medizinische/Pharmazeutische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001646http://purl.uni-rostock.de/rosdok/id00001646urn:nbn:de:gbv:28-diss2015-0196-5540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2015monographic20152015Universitätsbibliothek RostockRostock20152015The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.C-H activationPdNipurine-like compoundspyrazoleimidazoleUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00001646doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupExploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupgnd:1079688854gnd:132314614gnd:2147083-2gnd:1079688854gnd:132314614gnd:2147083-2rosdok_disshab_0000001467-d218849e39gnd:1079688854Ashot GevorgyanAshot Gevorgyanrosdok_disshab_0000001467-d218849e60gnd:132314614Prof. Dr. Peter LangerProf. Dr. Peter Langerrosdok_disshab_0000001467-d218849e75Prof. Dr. Maison WolfgangProf. Dr. Maison Wolfgangrosdok_disshab_0000001467-d218849e88gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAshot GevorgyanProf. Dr. Peter LangerProf. Dr. Maison WolfgangUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAshot GevorgyanProf. Dr. Peter LangerProf. Dr. Maison WolfgangUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAshot GevorgyanRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00001646http://purl.uni-rostock.de/rosdok/id00001646urn:nbn:de:gbv:28-diss2015-0196-5C-H activationPdNipurine-like compoundspyrazoleimidazoleThe present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.20152015epub.dissertation1 Dissertation_Gevorgyan_2015.pdf 11872500 3473dc2e913c7e1edb1965a498f6da1e rosdok/id00001646842372687MODS updated during RosDok migration in June 2021DissertationHochschulschrift1079688854AshotGevorgyan1989-VerfasserInautExploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupen132314614Prof. Dr.PeterLangerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MaisonWolfgangUniversität Hamburg, Fachbereich Chemie, Medizinische/Pharmazeutische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001646http://purl.uni-rostock.de/rosdok/id00001646urn:nbn:de:gbv:28-diss2015-0196-5540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2015monographic20152015Universitätsbibliothek RostockRostock20152015The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. 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Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.20152015[xslt]Saxonrosdok/id00001646https://purl.uni-rostock.de/rosdok/id0000164684237268710.18453/rosdok_id00001646urn:nbn:de:gbv:28-diss2015-0196-5Ashot GevorgyanGevorgyan AshotExploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupDissertationdoctoral thesisUniversität Rostock, 2015The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a…Ashot GevorgyanExploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro groupUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000016461079688854AshotGevorgyan1989-VerfasserInaut132314614Prof. Dr.PeterLangerUniversität Rostock, Institut für ChemieAkademischeR BetreuerIndgsProf. Dr.MaisonWolfgangUniversität Hamburg, Fachbereich Chemie, Medizinische/Pharmazeutische ChemieAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00001646[purl]http://purl.uni-rostock.de/rosdok/id00001646[urn]urn:nbn:de:gbv:28-diss2015-0196-5open_access20152015epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published