10.18453/rosdok_id00001837 Al-Ramadhani, Omar Mowafaq Younis Omar Mowafaq Younis Al-Ramadhani http://d-nb.info/gnd/1123243573 Schulz, Axel Axel Schulz http://d-nb.info/gnd/141478187 https://orcid.org/0000-0001-9060-7065 Rosenthal, Uwe Uwe Rosenthal http://d-nb.info/gnd/14076657X Universität Rostock 2016 540 Chemistry & allied sciences 2016 en http://purl.uni-rostock.de/rosdok/id00001837 urn:nbn:de:gbv:28-diss2017-0001-6 In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized.