mycoreobjectrosdok_disshab_0000001744rosdok_disshab_0000001744rosdokdisshabrosdok_derivate_00000371642023-08-08T10:08:02.188Z2017-06-28T13:04:49.699ZadministratoreditorDpublished1rosdok_derivate_0000037164truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id00001922892902728MODS updated during RosDok migration in June 2021DissertationHochschulschrift1136291121Lydia KatharinaVogt1989-VerfasserInautHydrogen generation from the chemical energy carrier methanolmechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst systemen112081908Prof. Dr.MatthiasBellerUniversität Rostock, Leibniz-Institut für Katalyse e. V.AkademischeR BetreuerIndgs1089591187Prof. Dr.GaborLaurenczyÉcole polytechnique fédérale de Lausanne, Institut des sciences et ingénierie chimiquesAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00001922http://purl.uni-rostock.de/rosdok/id00001922urn:nbn:de:gbv:28-diss2017-0086-0540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2017monographic20172017Universitätsbibliothek RostockRostock20172017This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. 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Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable catalyst system based on the base metal manganese was implemented for the low-temperature dehydrogenation of methanol.20172017[xslt]Saxonrosdok/id00001922https://purl.uni-rostock.de/rosdok/id0000192289290272810.18453/rosdok_id00001922urn:nbn:de:gbv:28-diss2017-0086-0Lydia Katharina VogtVogt Lydia KatharinaHydrogen generation from the chemical energy carrier methanol : mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst systemDissertationdoctoral thesisUniversität Rostock, 2017This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its…Lydia Katharina VogtHydrogen generation from the chemical energy carrier methanolmechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst systemUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id000019221136291121Lydia KatharinaVogt1989-VerfasserInaut112081908Prof. Dr.MatthiasBellerUniversität Rostock, Leibniz-Institut für Katalyse e. V.AkademischeR BetreuerIndgs1089591187Prof. Dr.GaborLaurenczyÉcole polytechnique fédérale de Lausanne, Institut des sciences et ingénierie chimiquesAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00001922[purl]http://purl.uni-rostock.de/rosdok/id00001922[urn]urn:nbn:de:gbv:28-diss2017-0086-0open_access20172017epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published