mycoreobjectrosdok_disshab_0000001883rosdok_disshab_0000001883rosdokdisshabrosdok_derivate_00000386532023-08-08T10:08:49.332Z2018-04-14T10:26:50.478ZadministratoreditorDpublished1rosdok_derivate_0000038653truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id000020611018696172MODS updated during RosDok migration in June 2021DissertationHochschulschrift114907289XAnneStrate, geb. Knorr1987-VerfasserInautSpectroscopic evidence for clusters of like-charged ions in ionic liquidsen136437524Prof. Dr.RalfLudwigUniversität Rostock, Institut für Chemie, Physikalische und Theoretische ChemieAkademischeR BetreuerIndgs120003813Prof. Dr.RolandWinterTechnische Universität Dortmund, Fakultät für Chemie und Chemische Biologie, Physikalische Chemie IAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00002061http://purl.uni-rostock.de/rosdok/id00002061urn:nbn:de:gbv:28-diss2018-0055-3540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2018monographic20172018Universitätsbibliothek RostockRostock20182018In this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. Finally, a theoretical approach of stabilizing the cationic cluster network by either neutral molecules or negatively charged counterions has been done.hydrogen bondingcationic cluster networklike-charge interactionIR spectroscopyDFT calculationsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00002061doctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisrfc5646:enrfc5646:enEnglischEnglishengengSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2licenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/Spectroscopic evidence for clusters of like-charged ions in ionic liquidsSpectroscopic evidence for clusters of like-charged ions in ionic liquidsgnd:114907289Xgnd:136437524gnd:120003813gnd:2147083-2gnd:114907289Xgnd:136437524gnd:120003813gnd:2147083-2rosdok_disshab_0000001883-d172536e39gnd:114907289XAnne Strate, geb. KnorrAnne Strate, geb. Knorrrosdok_disshab_0000001883-d172536e60gnd:136437524Prof. Dr. Ralf LudwigProf. Dr. Ralf Ludwigrosdok_disshab_0000001883-d172536e75gnd:120003813Prof. Dr. Roland WinterProf. Dr. Roland Winterrosdok_disshab_0000001883-d172536e90gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrProf. Dr. Ralf LudwigProf. Dr. Roland WinterUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrProf. Dr. Ralf LudwigProf. Dr. Roland WinterUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00002061http://purl.uni-rostock.de/rosdok/id00002061urn:nbn:de:gbv:28-diss2018-0055-3hydrogen bondingcationic cluster networklike-charge interactionIR spectroscopyDFT calculationsIn this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. Finally, a theoretical approach of stabilizing the cationic cluster network by either neutral molecules or negatively charged counterions has been done.20182018epub.dissertation1 Dissertation_Strate_2018.pdf 6034105 69eadd2ad9b113eb7e30e3f2d2586483 rosdok/id000020611018696172MODS updated during RosDok migration in June 2021DissertationHochschulschrift114907289XAnneStrate, geb. Knorr1987-VerfasserInautSpectroscopic evidence for clusters of like-charged ions in ionic liquidsen136437524Prof. Dr.RalfLudwigUniversität Rostock, Institut für Chemie, Physikalische und Theoretische ChemieAkademischeR BetreuerIndgs120003813Prof. Dr.RolandWinterTechnische Universität Dortmund, Fakultät für Chemie und Chemische Biologie, Physikalische Chemie IAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg10.18453/rosdok_id00002061http://purl.uni-rostock.de/rosdok/id00002061urn:nbn:de:gbv:28-diss2018-0055-3540 ChemieMathematisch-Naturwissenschaftliche Fakultätfrei zugänglich (Open Access)Lizenz Metadaten: CC0Nutzungsrechte erteiltalle Rechte vorbehaltenUniversität RostockRostock2018monographic20172018Universitätsbibliothek RostockRostock20182018In this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. 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KnorrAnne Strate, geb. Knorrrosdok_disshab_0000001883-d172536e60gnd:136437524Prof. Dr. Ralf LudwigProf. Dr. Ralf Ludwigrosdok_disshab_0000001883-d172536e75gnd:120003813Prof. Dr. Roland WinterProf. Dr. Roland Winterrosdok_disshab_0000001883-d172536e90gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrProf. Dr. Ralf LudwigProf. Dr. Roland WinterUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrProf. Dr. Ralf LudwigProf. Dr. Roland WinterUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätAnne Strate, geb. KnorrRostockUniversität Rostockepub.dissertation10.18453/rosdok_id00002061http://purl.uni-rostock.de/rosdok/id00002061urn:nbn:de:gbv:28-diss2018-0055-3hydrogen bondingcationic cluster networklike-charge interactionIR spectroscopyDFT calculationsIn this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. Finally, a theoretical approach of stabilizing the cationic cluster network by either neutral molecules or negatively charged counterions has been done.20182018[xslt]Saxonrosdok/id00002061https://purl.uni-rostock.de/rosdok/id00002061101869617210.18453/rosdok_id00002061urn:nbn:de:gbv:28-diss2018-0055-3Anne Strate, geb. KnorrStrate, geb. Knorr AnneSpectroscopic evidence for clusters of like-charged ions in ionic liquidsDissertationdoctoral thesisUniversität Rostock, 2018In this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like…Anne Strate, geb. KnorrSpectroscopic evidence for clusters of like-charged ions in ionic liquidsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00002061114907289XAnneStrate, geb. Knorr1987-VerfasserInaut136437524Prof. Dr.RalfLudwigUniversität Rostock, Institut für Chemie, Physikalische und Theoretische ChemieAkademischeR BetreuerIndgs120003813Prof. Dr.RolandWinterTechnische Universität Dortmund, Fakultät für Chemie und Chemische Biologie, Physikalische Chemie IAkademischeR BetreuerIndgs2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[doi]10.18453/rosdok_id00002061[purl]http://purl.uni-rostock.de/rosdok/id00002061[urn]urn:nbn:de:gbv:28-diss2018-0055-3open_access20182018epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published