1 Jaime_Dissertation_2018.pdf 3154008 492f93b75f10a5019180b1da1032f46e rosdok/id00002353 1042003475 Oau 2018-12-06 2023-08-05T19:11:24Z rda Converted from PICA to MODS using Pica2Mods XSLT Transformer 2.7 [SCM: "0c0e7a3c226a4a0cbcbec39b493c3c5257339ab8" "v2.7" "2023-08-04T00:00:00+0200"] with mode 'DEFAULT'. Dissertation Hochschulschrift Selective oxidation of C16 macrocyclic diene to epoxides and ketones In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone. Diego Alberto Jaime Treviño 1989 - VerfasserIn aut 1149164220 Andreas Martin 1955 - AkademischeR BetreuerIn dgs 1024432599 Ulf Prüße 1966 - AkademischeR BetreuerIn dgs 122104986 38329-6 Universität Rostock 1419 - Grad-verleihende Institution dgg 2147083-2 Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät Grad-verleihende Institution dgg http://purl.uni-rostock.de/rosdok/id00002353 urn:nbn:de:gbv:28-diss2018-0180-6 10.18453/rosdok_id00002353 540 Chemie Mathematisch-Naturwissenschaftliche Fakultät alle Rechte vorbehalten Nutzungsrechte erteilt Lizenz Metadaten: CC0 frei zugänglich (Open Access) en 2017 Universität Rostock Rostock monographic 2017 2017 2018 Universitätsbibliothek Rostock Rostock 2018 Universitätsbibliothek Rostock http://purl.uni-rostock.de/rosdok/id00002353 vorgelegt von Lic. Diego A. Jaime Trevin̂o Epoxidation 2018-12-06T10:03:43.077Z 2023-08-08T10:09:34.061Z 2023-08-18T10:09:34.066Z {"identifier":"rosdok/id00002353","type":"local_id","additional":"","service":"MCRLocalID","created":"2018-12-06T10:03:43.121Z"} editorD {"identifier":"http://purl.uni-rostock.de/rosdok/id00002353","type":"purl","additional":"","service":"RosDokPURL","created":"2018-12-06T10:23:11.546Z","registered":"2018-12-06T10:23:11.546Z"} {"identifier":"10.18453/rosdok_id00002353","type":"doi","additional":"","service":"RosDokDOI","created":"2018-12-06T10:23:13.002Z","registered":"2018-12-06T10:23:13.002Z"} {"identifier":"urn:nbn:de:gbv:28-diss2018-0180-6","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2018-12-06T10:03:43.150Z","registered":"2018-12-07T03:17:55.887Z"} administrator