mycoreobjectrosdok_disshab_0000002008rosdok_disshab_0000002008rosdokdisshabrosdok_derivate_00000577022023-08-08T10:09:34.061Z2018-12-06T10:03:43.077ZadministratoreditorDpublished1rosdok_derivate_0000057702truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id000023531042003475Oau2018-12-062023-08-05T19:11:24ZrdaConverted from PICA to MODS using Pica2Mods XSLT Transformer 2.7 [SCM: "0c0e7a3c226a4a0cbcbec39b493c3c5257339ab8" "v2.7" "2023-08-04T00:00:00+0200"] with mode 'DEFAULT'.DissertationHochschulschriftSelective oxidation of C16 macrocyclic diene to epoxides and ketonesIn the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.Diego AlbertoJaime Treviño1989 -VerfasserInaut1149164220AndreasMartin1955 -AkademischeR BetreuerIndgs1024432599UlfPrüße1966 -AkademischeR BetreuerIndgs12210498638329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttp://purl.uni-rostock.de/rosdok/id00002353urn:nbn:de:gbv:28-diss2018-0180-610.18453/rosdok_id00002353540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2017Universität RostockRostockmonographic201720172018Universitätsbibliothek RostockRostock2018Universitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00002353vorgelegt von Lic. Diego A. Jaime Trevin̂oEpoxidationdoctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2licenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2rfc5646:enrfc5646:enEnglischEnglishengengSelective oxidation of C16 macrocyclic diene to epoxides and ketonesSelective oxidation of C16 macrocyclic diene to epoxides and ketonesgnd:1149164220gnd:1024432599gnd:122104986gnd:38329-6gnd:2147083-2gnd:1149164220gnd:1024432599gnd:122104986gnd:38329-6gnd:2147083-2rosdok_disshab_0000002008-d2858746e52gnd:1149164220Diego Alberto Jaime TreviñoDiego Alberto Jaime Treviñorosdok_disshab_0000002008-d2858746e66gnd:1024432599Andreas MartinAndreas Martinrosdok_disshab_0000002008-d2858746e80gnd:122104986Ulf PrüßeUlf Prüßerosdok_disshab_0000002008-d2858746e94gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000002008-d2858746e106gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoAndreas MartinUlf PrüßeUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoAndreas MartinUlf PrüßeUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoRostockUniversität Rostockepub.dissertationhttp://purl.uni-rostock.de/rosdok/id00002353urn:nbn:de:gbv:28-diss2018-0180-610.18453/rosdok_id00002353EpoxidationIn the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.20172017vorgelegt von Lic. Diego A. Jaime Trevin̂oepub.dissertation1 Jaime_Dissertation_2018.pdf 3154008 492f93b75f10a5019180b1da1032f46e rosdok/id000023531042003475Oau2018-12-062023-08-05T19:11:24ZrdaConverted from PICA to MODS using Pica2Mods XSLT Transformer 2.7 [SCM: "0c0e7a3c226a4a0cbcbec39b493c3c5257339ab8" "v2.7" "2023-08-04T00:00:00+0200"] with mode 'DEFAULT'.DissertationHochschulschriftSelective oxidation of C16 macrocyclic diene to epoxides and ketonesIn the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.Diego AlbertoJaime Treviño1989 -VerfasserInaut1149164220AndreasMartin1955 -AkademischeR BetreuerIndgs1024432599UlfPrüße1966 -AkademischeR BetreuerIndgs12210498638329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttp://purl.uni-rostock.de/rosdok/id00002353urn:nbn:de:gbv:28-diss2018-0180-610.18453/rosdok_id00002353540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2017Universität RostockRostockmonographic201720172018Universitätsbibliothek RostockRostock2018Universitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00002353vorgelegt von Lic. Diego A. Jaime Trevin̂oEpoxidation 2018-12-06T10:03:43.077Z 2023-08-08T10:09:34.061Z 2023-08-18T10:09:34.066Z {"identifier":"rosdok/id00002353","type":"local_id","additional":"","service":"MCRLocalID","created":"2018-12-06T10:03:43.121Z"} editorD {"identifier":"http://purl.uni-rostock.de/rosdok/id00002353","type":"purl","additional":"","service":"RosDokPURL","created":"2018-12-06T10:23:11.546Z","registered":"2018-12-06T10:23:11.546Z"} {"identifier":"10.18453/rosdok_id00002353","type":"doi","additional":"","service":"RosDokDOI","created":"2018-12-06T10:23:13.002Z","registered":"2018-12-06T10:23:13.002Z"} {"identifier":"urn:nbn:de:gbv:28-diss2018-0180-6","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2018-12-06T10:03:43.150Z","registered":"2018-12-07T03:17:55.887Z"} administratorfulltextfile/rosdok_disshab_0000002008/rosdok_derivate_0000057702/Jaime_Dissertation_2018.pdfSelective oxidation of C16 macrocyclic diene to epoxides and ketonesSelective oxidation of C16 macrocyclic diene to epoxides and ketonesgnd:1149164220gnd:1024432599gnd:122104986gnd:38329-6gnd:2147083-2gnd:1149164220gnd:1024432599gnd:122104986gnd:38329-6gnd:2147083-2rosdok_disshab_0000002008-d2858746e52gnd:1149164220Diego Alberto Jaime TreviñoDiego Alberto Jaime Treviñorosdok_disshab_0000002008-d2858746e66gnd:1024432599Andreas MartinAndreas Martinrosdok_disshab_0000002008-d2858746e80gnd:122104986Ulf PrüßeUlf Prüßerosdok_disshab_0000002008-d2858746e94gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000002008-d2858746e106gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoAndreas MartinUlf PrüßeUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoAndreas MartinUlf PrüßeUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDiego Alberto Jaime TreviñoRostockUniversität Rostockepub.dissertationhttp://purl.uni-rostock.de/rosdok/id00002353urn:nbn:de:gbv:28-diss2018-0180-610.18453/rosdok_id00002353EpoxidationIn the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.20172017vorgelegt von Lic. Diego A. Jaime Trevin̂o[xslt]Saxonrosdok/id00002353https://purl.uni-rostock.de/rosdok/id00002353104200347510.18453/rosdok_id00002353urn:nbn:de:gbv:28-diss2018-0180-6Diego Alberto Jaime TreviñoJaime Treviño Diego AlbertoSelective oxidation of C16 macrocyclic diene to epoxides and ketonesDissertationdoctoral thesisUniversität Rostock, 2017In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst…Diego Alberto Jaime TreviñoSelective oxidation of C16 macrocyclic diene to epoxides and ketonesUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00002353Diego AlbertoJaime Treviño1989 -VerfasserInaut1149164220AndreasMartin1955 -AkademischeR BetreuerIndgs1024432599UlfPrüße1966 -AkademischeR BetreuerIndgs12210498638329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[purl]http://purl.uni-rostock.de/rosdok/id00002353[urn]urn:nbn:de:gbv:28-diss2018-0180-6[doi]10.18453/rosdok_id00002353open_access20172017epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published