mycoreobjectrosdok_disshab_0000002693rosdok_disshab_0000002693rosdokdisshabrosdok_derivate_00001119362023-08-08T10:13:51.794Z2022-02-17T07:39:56.471ZadministratoreditorMSpublished1rosdok_derivate_0000111936truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id000034921789926815Oau2022-02-172023-08-05T19:19:24ZrdaConverted from PICA to MODS using Pica2Mods XSLT Transformer 2.7 [SCM: "0c0e7a3c226a4a0cbcbec39b493c3c5257339ab8" "v2.7" "2023-08-04T00:00:00+0200"] with mode 'DEFAULT'.DissertationHochschulschriftDevelopment of 3d metal catalysts for redox reactionsHerein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.DavidLeonard1995 -VerfasserInaut12519579940000-0002-3471-2060MatthiasBeller1962 -AkademischeR BetreuerIndgs1120819080000-0001-5709-0965Leibniz Institute for CatalysisShoubhikDas1980 -AkademischeR BetreuerIndgs10189784290000-0002-4577-438XUniversity of Antwerp38329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttp://purl.uni-rostock.de/rosdok/id00003492urn:nbn:de:gbv:28-rosdok_id00003492-410.18453/rosdok_id00003492500 Naturwissenschaften540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2021Universität RostockRostockmonographic202120212022Universitätsbibliothek RostockRostock2022Universitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00003492Enthält ZeitschriftenartikelMatthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp)[{"affil":"Leibniz Institute for Catalysis","name":"Beller, Matthias"},{"affil":"University of Antwerp","name":"Das, Shoubhik"}]vorgelegt von David LeonardRedoxreaktionKatalysatorUnedles MetallLeibniz Institute for CatalysisBeller, MatthiasUniversity of AntwerpDas, Shoubhikdoctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisSDNB:500SDNB:500500 Naturwissenschaften500 Natural sciencesSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2licenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2rfc5646:enrfc5646:enEnglischEnglishengengDevelopment of 3d metal catalysts for redox reactionsDevelopment of 3d metal catalysts for redox reactionsgnd:1251957994orcid:0000-0002-3471-2060gnd:112081908orcid:0000-0001-5709-0965gnd:1018978429orcid:0000-0002-4577-438Xgnd:38329-6gnd:2147083-2gnd:1251957994orcid:0000-0002-3471-2060gnd:112081908orcid:0000-0001-5709-0965gnd:1018978429orcid:0000-0002-4577-438Xgnd:38329-6gnd:2147083-2rosdok_disshab_0000002693-d3865099e52gnd:1251957994orcid:0000-0002-3471-2060David LeonardDavid Leonardrosdok_disshab_0000002693-d3865099e68gnd:112081908orcid:0000-0001-5709-0965Matthias BellerMatthias Bellerrosdok_disshab_0000002693-d3865099e85gnd:1018978429orcid:0000-0002-4577-438XShoubhik DasShoubhik Dasrosdok_disshab_0000002693-d3865099e102gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000002693-d3865099e114gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardMatthias BellerShoubhik DasUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardMatthias BellerShoubhik DasUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardRostockUniversität Rostockepub.dissertationhttp://purl.uni-rostock.de/rosdok/id00003492urn:nbn:de:gbv:28-rosdok_id00003492-410.18453/rosdok_id00003492RedoxreaktionKatalysatorUnedles MetallHerein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.20212021Enthält ZeitschriftenartikelMatthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp)[{"affil":"Leibniz Institute for Catalysis","name":"Beller, Matthias"},{"affil":"University of Antwerp","name":"Das, Shoubhik"}]vorgelegt von David Leonardepub.dissertation1 Leonard_Dissertation_2022.pdf 7205114 590c16b2e032f1057d11ae18598e4a98 rosdok/id000034921789926815Oau2022-02-172023-08-05T19:19:24ZrdaConverted from PICA to MODS using Pica2Mods XSLT Transformer 2.7 [SCM: "0c0e7a3c226a4a0cbcbec39b493c3c5257339ab8" "v2.7" "2023-08-04T00:00:00+0200"] with mode 'DEFAULT'.DissertationHochschulschriftDevelopment of 3d metal catalysts for redox reactionsHerein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.DavidLeonard1995 -VerfasserInaut12519579940000-0002-3471-2060MatthiasBeller1962 -AkademischeR BetreuerIndgs1120819080000-0001-5709-0965Leibniz Institute for CatalysisShoubhikDas1980 -AkademischeR BetreuerIndgs10189784290000-0002-4577-438XUniversity of Antwerp38329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttp://purl.uni-rostock.de/rosdok/id00003492urn:nbn:de:gbv:28-rosdok_id00003492-410.18453/rosdok_id00003492500 Naturwissenschaften540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2021Universität RostockRostockmonographic202120212022Universitätsbibliothek RostockRostock2022Universitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00003492Enthält ZeitschriftenartikelMatthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp)[{"affil":"Leibniz Institute for Catalysis","name":"Beller, Matthias"},{"affil":"University of Antwerp","name":"Das, Shoubhik"}]vorgelegt von David LeonardRedoxreaktionKatalysatorUnedles Metall Leibniz Institute for Catalysis Beller, Matthias University of Antwerp Das, Shoubhik 2022-02-17T07:39:56.471Z 2023-08-08T10:13:51.794Z 2023-08-18T10:13:51.799Z {"identifier":"rosdok/id00003492","type":"local_id","additional":"","service":"MCRLocalID","created":"2022-02-17T07:39:56.506Z","registered":"2022-02-17T07:39:56.506Z"} editorMS {"identifier":"urn:nbn:de:gbv:28-rosdok_id00003492-4","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2022-02-17T07:39:56.519Z","registered":"2022-02-17T16:18:10.953Z"} administratorfulltextfile/rosdok_disshab_0000002693/rosdok_derivate_0000111936/Leonard_Dissertation_2022.pdfDevelopment of 3d metal catalysts for redox reactionsDevelopment of 3d metal catalysts for redox reactionsgnd:1251957994orcid:0000-0002-3471-2060gnd:112081908orcid:0000-0001-5709-0965gnd:1018978429orcid:0000-0002-4577-438Xgnd:38329-6gnd:2147083-2gnd:1251957994orcid:0000-0002-3471-2060gnd:112081908orcid:0000-0001-5709-0965gnd:1018978429orcid:0000-0002-4577-438Xgnd:38329-6gnd:2147083-2rosdok_disshab_0000002693-d3865099e52gnd:1251957994orcid:0000-0002-3471-2060David LeonardDavid Leonardrosdok_disshab_0000002693-d3865099e68gnd:112081908orcid:0000-0001-5709-0965Matthias BellerMatthias Bellerrosdok_disshab_0000002693-d3865099e85gnd:1018978429orcid:0000-0002-4577-438XShoubhik DasShoubhik Dasrosdok_disshab_0000002693-d3865099e102gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000002693-d3865099e114gnd:2147083-2Universität Rostock Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardMatthias BellerShoubhik DasUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardMatthias BellerShoubhik DasUniversität RostockUniversität Rostock Mathematisch-Naturwissenschaftliche FakultätDavid LeonardRostockUniversität Rostockepub.dissertationhttp://purl.uni-rostock.de/rosdok/id00003492urn:nbn:de:gbv:28-rosdok_id00003492-410.18453/rosdok_id00003492RedoxreaktionKatalysatorUnedles MetallHerein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.20212021Enthält ZeitschriftenartikelMatthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp)[{"affil":"Leibniz Institute for Catalysis","name":"Beller, Matthias"},{"affil":"University of Antwerp","name":"Das, Shoubhik"}]vorgelegt von David Leonard[xslt]Saxonrosdok/id00003492https://purl.uni-rostock.de/rosdok/id00003492178992681510.18453/rosdok_id00003492urn:nbn:de:gbv:28-rosdok_id00003492-4David LeonardLeonard DavidDevelopment of 3d metal catalysts for redox reactionsDissertationdoctoral thesisUniversität Rostock, 2021Herein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of…David LeonardDevelopment of 3d metal catalysts for redox reactionsUniversitätsbibliothek Rostockhttp://purl.uni-rostock.de/rosdok/id00003492DavidLeonard1995 -VerfasserInaut12519579940000-0002-3471-2060MatthiasBeller1962 -AkademischeR BetreuerIndgs1120819080000-0001-5709-0965Leibniz Institute for CatalysisShoubhikDas1980 -AkademischeR BetreuerIndgs10189784290000-0002-4577-438XUniversity of Antwerp38329-6Universität Rostock1419 -Grad-verleihende Institutiondgg2147083-2Universität RostockMathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[purl]http://purl.uni-rostock.de/rosdok/id00003492[urn]urn:nbn:de:gbv:28-rosdok_id00003492-4[doi]10.18453/rosdok_id00003492open_access20212021epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:500SDNB:540institution:unirostock.mnfstate:published