10.18453/rosdok_id00003565 Sun, Yanjun Yanjun Sun http://d-nb.info/gnd/1228998795 Universität Rostock 2020 540 Chemistry & allied sciences 2020 en http://purl.uni-rostock.de/rosdok/id00003565 urn:nbn:de:gbv:28-rosdok_id00003565-2 Zirconium-based metal-organic frameworks (Zr-MOFs) of different pore sizes and structure were synthesized and used for the preparation of the Rh-supported catalysts. The catalytic performance was studied in the hydroformylation of olefins to the corresponding aldehydes. A series of n-alk-1-enes of different chain length and bulky olefins with different size was used to study the influence of the pore size and structure. The results show that the Zr-MOF-based catalysts are very active and show high aldehyde selectivity.