mycoreobjectrosdok_disshab_0000003288rosdok_disshab_0000003288rosdokdisshabrosdok_derivate_00002250992025-07-21T14:56:12.067Z2025-07-21T14:43:36.255ZMCRJANITOReditorFGpublished1rosdok_derivate_0000225099truetruederivate_types:fulltextVolltextfulltextwf_edit_epub wf_register_epubstate:publishedstate:publishedveröffentlichtpublishedrosdok/id000048771931412952Oau2025-07-212025-07-21T14:47:11ZrdaConverted from PICA to MODS using Pica2MODS XSLT Transformer 2.10 [SCM: "f6c168af690edb7cb65ef34e4a2bf7f8714c5d38" "v2.10" "2024-03-28T14:43:08+0100"] with mode 'DEFAULT'.DissertationHochschulschriftHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesThe first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.SihanLi1995 -VerfasserInaut1372038248TorstenBeweries1982 -AkademischeR BetreuerIndgs1363494470000-0002-2416-8874Leibniz-Institut für Katalyse e.V.DominikMunz1982 -AkademischeR BetreuerIndgs103584141XSaarland University, Inorganic Chemistry: Coordination Chemistry38329-6Universität Rostock1419 - 19761990 -Grad-verleihende Institutiondgg2147083-2Universität Rostock. Mathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttps://purl.uni-rostock.de/rosdok/id00004877urn:nbn:de:gbv:28-rosdok_id00004877-810.18453/rosdok_id00004877540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2024Universität RostockRostockmonographic202420242025Universitätsbibliothek RostockRostock2025Universitätsbibliothek Rostockhttps://purl.uni-rostock.de/rosdok/id00004877Enthält ZeitschriftenartikelTorsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)[{"name":"Beweries, Torsten","affil":"Leibniz-Institut für Katalyse e.V."},{"name":"Munz, Dominik","affil":"Saarland University, Inorganic Chemistry: Coordination Chemistry"}]Dissertation, Universität Rostock, 2024, Kumulative Dissertationvorgelegt von Sihan LiBeweries, TorstenLeibniz-Institut für Katalyse e.V.Munz, DominikSaarland University, Inorganic Chemistry: Coordination Chemistrydoctype:epubdoctype:epubDokumenttypDocument typedoctype:epub.dissertationdoctype:epub.dissertationDissertationdoctoral thesisdiniPublType:doctoralThesis diniPublType2022:PhDThesis XMetaDissPlusThesisLevel:thesis.doctoralinfo:eu-repo/semantics/doctoralThesisdocumentnatureOfContent:ppn_105825778natureOfContent:ppn_105825778HochschulschriftdiniPublType2022:DoctoralThesisdiniPublType2022:DoctoralThesisDissertation oder HabilitationDoctoral thesisDRIVERdiniPublType2022:PhDThesisdiniPublType2022:PhDThesisDissertationPhD thesisKDSF (Pu34)XMetaDissPlusThesisLevel:thesis.doctoralXMetaDissPlusThesisLevel:thesis.doctoralDoktorarbeitdoctoral thesisSDNB:540SDNB:540540 Chemie540 Chemistry & allied sciencesinstitution:unirostockinstitution:unirostockUniversität RostockUniversity of RostockUniversität RostockUniversität RostockUni.Rostockhttp://d-nb.info/gnd/38329-6institution:unirostock.mnfinstitution:unirostock.mnfMathematisch-Naturwissenschaftliche FakultätFaculty of Mathematics and Natural SciencesUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätMathematisch-Natur-<br />wissenschaftliche FakultätUni.Rostock.Fakultaet.MNFhttp://d-nb.info/gnd/2147083-2licenseinfo:worklicenseinfo:workWerkworklicenseinfo:work.rightsreservedlicenseinfo:work.rightsreservedalle Rechte vorbehaltenall rights reserved/creativecommons/r/reserved/0.9/88x31.png[DE-28]Urheberrechtsschutz 1.0$gRights Statements$uhttp://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/http://rightsstatements.org/vocab/InC/1.0/licenseinfo:depositlicenseinfo:depositVeröffentlichungsgenehmigungpermission to storelicenseinfo:deposit.rightsgrantedlicenseinfo:deposit.rightsgrantedNutzungsrechte erteiltrights grantedlicenseinfo:metadatalicenseinfo:metadataLizenzen für Metadatenlicenseinfo:metadata.cc0licenseinfo:metadata.cc0Lizenz Metadaten: CC0license metadata: CC0/creativecommons/p/zero/1.0/88x31.pnghttps://creativecommons.org/publicdomain/zero/1.0/accesscondition:openaccessaccesscondition:openaccessfrei zugänglich (Open Access)open accesshttp://purl.org/coar/access_right/c_abf2OAfreeinfo:eu-repo/semantics/openAccess[DE-28]Open Access$gControlled Vocabulary for Access Rights$uhttp://purl.org/coar/access_right/c_abf2rfc5646:enrfc5646:enEnglischEnglishengengHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesgnd:1372038248gnd:136349447orcid:0000-0002-2416-8874gnd:103584141Xgnd:38329-6gnd:2147083-2gnd:1372038248gnd:136349447orcid:0000-0002-2416-8874gnd:103584141Xgnd:38329-6gnd:2147083-2rosdok_disshab_0000003288-d479126e52gnd:1372038248Sihan LiSihan Lirosdok_disshab_0000003288-d479126e66gnd:136349447orcid:0000-0002-2416-8874Torsten BeweriesTorsten Beweriesrosdok_disshab_0000003288-d479126e83gnd:103584141XDominik MunzDominik Munzrosdok_disshab_0000003288-d479126e98gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000003288-d479126e112gnd:2147083-2Universität Rostock. Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiTorsten BeweriesDominik MunzUniversität RostockUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiTorsten BeweriesDominik MunzUniversität RostockUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiRostockUniversität Rostockepub.dissertationhttps://purl.uni-rostock.de/rosdok/id00004877urn:nbn:de:gbv:28-rosdok_id00004877-810.18453/rosdok_id00004877The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.20242024Enthält ZeitschriftenartikelTorsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)[{"name":"Beweries, Torsten","affil":"Leibniz-Institut für Katalyse e.V."},{"name":"Munz, Dominik","affil":"Saarland University, Inorganic Chemistry: Coordination Chemistry"}]Dissertation, Universität Rostock, 2024, Kumulative Dissertationvorgelegt von Sihan Liepub.dissertation1 Li_Dissertation_2025.pdf 31436700 b16abb656a4bd97ed019dbf12af5a6d0 rosdok/id000048771931412952Oau2025-07-212025-07-21T14:47:11ZrdaConverted from PICA to MODS using Pica2MODS XSLT Transformer 2.10 [SCM: "f6c168af690edb7cb65ef34e4a2bf7f8714c5d38" "v2.10" "2024-03-28T14:43:08+0100"] with mode 'DEFAULT'.DissertationHochschulschriftHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesThe first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.SihanLi1995 -VerfasserInaut1372038248TorstenBeweries1982 -AkademischeR BetreuerIndgs1363494470000-0002-2416-8874Leibniz-Institut für Katalyse e.V.DominikMunz1982 -AkademischeR BetreuerIndgs103584141XSaarland University, Inorganic Chemistry: Coordination Chemistry38329-6Universität Rostock1419 - 19761990 -Grad-verleihende Institutiondgg2147083-2Universität Rostock. Mathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgghttps://purl.uni-rostock.de/rosdok/id00004877urn:nbn:de:gbv:28-rosdok_id00004877-810.18453/rosdok_id00004877540 ChemieMathematisch-Naturwissenschaftliche Fakultätalle Rechte vorbehaltenNutzungsrechte erteiltLizenz Metadaten: CC0frei zugänglich (Open Access)en2024Universität RostockRostockmonographic202420242025Universitätsbibliothek RostockRostock2025Universitätsbibliothek Rostockhttps://purl.uni-rostock.de/rosdok/id00004877Enthält ZeitschriftenartikelTorsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)[{"name":"Beweries, Torsten","affil":"Leibniz-Institut für Katalyse e.V."},{"name":"Munz, Dominik","affil":"Saarland University, Inorganic Chemistry: Coordination Chemistry"}]Dissertation, Universität Rostock, 2024, Kumulative Dissertationvorgelegt von Sihan Li Beweries, Torsten Leibniz-Institut für Katalyse e.V. Munz, Dominik Saarland University, Inorganic Chemistry: Coordination Chemistry 2025-07-21T14:43:36.255Z 2025-07-21T14:56:12.067Z 2025-07-31T14:56:12.076Z editorFG {"identifier":"rosdok/id00004877","type":"local_id","additional":"","service":"MCRLocalID","created":"2025-07-21T14:43:36.287Z"} {"identifier":"urn:nbn:de:gbv:28-rosdok_id00004877-8","type":"dnbUrn","additional":"","service":"RosDokURN","created":"2025-07-21T14:43:36.295Z"} {"identifier":"https://purl.uni-rostock.de/rosdok/id00004877","type":"purl","additional":"","service":"RosDokPURL","created":"2025-07-21T14:43:36.298Z","registrationStarted":"2025-07-21T14:56:10.577Z"} {"identifier":"10.18453/rosdok_id00004877","type":"doi","additional":"","service":"RosDokDOI","created":"2025-07-21T14:43:36.302Z","registrationStarted":"2025-07-21T14:56:10.336Z","registered":"2025-07-21T14:56:12.065Z"} MCRJANITORfulltextfile/rosdok_disshab_0000003288/rosdok_derivate_0000225099/Li_Dissertation_2025.pdfHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesgnd:1372038248gnd:136349447orcid:0000-0002-2416-8874gnd:103584141Xgnd:38329-6gnd:2147083-2gnd:1372038248gnd:136349447orcid:0000-0002-2416-8874gnd:103584141Xgnd:38329-6gnd:2147083-2rosdok_disshab_0000003288-d479126e52gnd:1372038248Sihan LiSihan Lirosdok_disshab_0000003288-d479126e66gnd:136349447orcid:0000-0002-2416-8874Torsten BeweriesTorsten Beweriesrosdok_disshab_0000003288-d479126e83gnd:103584141XDominik MunzDominik Munzrosdok_disshab_0000003288-d479126e98gnd:38329-6Universität RostockUniversität Rostockrosdok_disshab_0000003288-d479126e112gnd:2147083-2Universität Rostock. Mathematisch-Naturwissenschaftliche FakultätUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiTorsten BeweriesDominik MunzUniversität RostockUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiTorsten BeweriesDominik MunzUniversität RostockUniversität Rostock. Mathematisch-Naturwissenschaftliche FakultätSihan LiRostockUniversität Rostockepub.dissertationhttps://purl.uni-rostock.de/rosdok/id00004877urn:nbn:de:gbv:28-rosdok_id00004877-810.18453/rosdok_id00004877The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.20242024Enthält ZeitschriftenartikelTorsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)[{"name":"Beweries, Torsten","affil":"Leibniz-Institut für Katalyse e.V."},{"name":"Munz, Dominik","affil":"Saarland University, Inorganic Chemistry: Coordination Chemistry"}]Dissertation, Universität Rostock, 2024, Kumulative Dissertationvorgelegt von Sihan Li[xslt]Saxonrosdok/id00004877https://purl.uni-rostock.de/rosdok/id00004877193141295210.18453/rosdok_id00004877urn:nbn:de:gbv:28-rosdok_id00004877-8Sihan LiLi SihanHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesDissertationdoctoral thesisUniversität Rostock, 2024The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these…Sihan LiHighly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienesUniversitätsbibliothek Rostockhttps://purl.uni-rostock.de/rosdok/id00004877SihanLi1995 -VerfasserInaut1372038248TorstenBeweries1982 -AkademischeR BetreuerIndgs1363494470000-0002-2416-8874Leibniz-Institut für Katalyse e.V.DominikMunz1982 -AkademischeR BetreuerIndgs103584141XSaarland University, Inorganic Chemistry: Coordination Chemistry38329-6Universität Rostock1419 - 19761990 -Grad-verleihende Institutiondgg2147083-2Universität Rostock. Mathematisch-Naturwissenschaftliche FakultätGrad-verleihende Institutiondgg[purl]https://purl.uni-rostock.de/rosdok/id00004877[urn]urn:nbn:de:gbv:28-rosdok_id00004877-8[doi]10.18453/rosdok_id00004877open_access20242024epoch:21th_centuryrfc5646:endoctype:epub.dissertationaccesscondition:openaccessSDNB:540institution:unirostock.mnfstate:published