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Thomas Schmidt

Mechanistische Untersuchungen zur homogenen Rhodiumkomplex-katalysierten enantioselektiven Hydrierung prochiraler Olefine

Universität Rostock, 2007

Abstract: This Dissertation deals with mechanistic aspects of the enantioselective hydrogenation of different prochiral olefins (dehydroamino acid derivatives, enamides, itaconic acid derivatives).With the help of kinetic investigations of the hydrogenation, NMR spectroscopic studies as well as X-ray structures of intermediates of the reactions, contributions to the reaction sequences of the respective hydrogenations shall be provided. For six of the investigated systems support for the validity of the major-minor principle was found.

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