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Gnuni Karapetyan

An excursion into the chemistry of N- and C-glycosides of D-galacturonic acid

Universität Rostock, 2008

Abstract: In the present work the synthesis of D-galacturonic acid N- and C-glycosides is described. Several protecting strategies were investigated for the synthesis and structural characterization of 1-azido and C-allyl galacturonates as suitable building blocks. Derivatization of azido and C-allyl moieties is described resulting in biotinylated compounds which can be used for the synthesis of labelled pectin fragments. Such biotinylated fragments are useful tools in biochemical assays.

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