New applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studies

Dirk Hollmann

doi:10.18453/rosdok_id00000409

Dirk Hollmann

New applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studies

Universität Rostock, 2008

https://doi.org/10.18453/rosdok_id00000409

Abstract: This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed.

doctoral thesis free access

title:

New applications of the borrowing hydrogen methodology - selective synthesis of amines and mechanistic studies

contributing persons:

Dirk Hollmann[VerfasserIn]
	137495889
Matthias Beller , Prof. Dr.[AkademischeR BetreuerIn]
Jonathan M. J. Williams , Prof. Dr.[AkademischeR BetreuerIn]
Lutz Ackermann[AkademischeR BetreuerIn]

contributing corporate bodies:

Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

abstract:

This cumulative thesis deals with the application of the Borrowing Hydrogen methodology in organic synthesis. During my research, the Borrowing Hydrogen methodology was applied in the synthesis of secondary and tertiary amines starting from secondary alcohols by C-O activation. Furthermore, I was able to introduce the selective synthesis of monoalkylated aryl amines using aliphatic amines by C-N activation. This new method was continuously applied in the alkylation of t-alkyl amines. Additionally, mechanistic studies in the activation and deactivation of the Shvo catalyst were performed. [English]

document type:

doctoral thesis

institution:

Faculty of Mathematics and Natural Sciences

language:

English

subject class (DDC):

540 Chemistry & allied sciences

publication /
production:

Rostock: Universität Rostock

2008

identifiers: