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Munawar Hussain

Domino Twofold Heck / 6p-Electrocyclization and Regioselective Palladium(0)-Catalyzed Reactions of Brominated Indoles, Furans, Naphthoquinone and 2,4,5,6-Tetrachloropyrimidine

Universität Rostock, 2010

Abstract: I have synthesized functionalized carbazoles and benzofurans based on domino twofold Heck / 6pi-electrocyclization reactions. Functionalized anthraquinones, fluorenones and benzocoumarines were also prepared by this methodology. Regioselctive Suzuki-Miyaura cross-coupling reactions of 2,4,5,6-tetrachloropyrimidine and 2,3,4,5-tetrabromofuran provided an expedient synthesis of mono-, di-, tri- and tetraaryl-pyrimidines and di- and tetraarylfurans.

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