| title: |
| Synthesis of Functionalized Benzophenones and Terphenyls based on Site-Selective Suzuki-Miyaura
Reactions of Bis(triflates) of various Hydroxylated Benzophenones and Benzoates |
|
| contributing persons: |
| Muhammad Nawaz[VerfasserIn] |
 |
1011739852 |
| Peter Langer
, Prof. Dr.[AkademischeR BetreuerIn] |
| Jürgen Voss
, Prof. Dr.[AkademischeR BetreuerIn] |
|
| contributing corporate bodies: |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
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| abstract: |
|
The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of
2,4′-dihydroxybenzophenones afforded 2,4′-diarylbenzophenones. The Suzuki-Miyaura
reaction of the bis(triflate) of 3,4-dihydroxybenzophenone with two equivalents of
boronic acids gave 3,4-diarylbenzophenones. The Sonogashira cross-coupling reactions
of the same substrate display remarkable compatibility with Suzuki reactions.The palladium(0)-catalyzed
Suzuki cross-coupling reaction of the bis(triflates) of methyl 2,5-dihydroxybenzoate
and methyl 2,4-dihydroxybenzoate afforded p-terphenyls and m-terphenyls respectively.
[English] |
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| document type: |
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| institution: |
| Faculty of Mathematics and Natural Sciences |
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| language: |
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| subject class (DDC): |
| 540 Chemistry & allied sciences |
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| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2010
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| identifiers: |
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| access condition: |
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| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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|
| RosDok id: |
rosdok_disshab_0000000640 |
| created / modified: |
13.05.2011 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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