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Ihsan Ullah

Synthesis of 3-aryl-3,4-Dihydroisocoumarins and sterically encumbered Biaryls by [3+3] Cyclocondensation Reactions and synthesis of Functionalized Fluoranthenes, trifluoromethyl-Substituted Di- and Terphenyls and tetraaryl-p-Benzoquinones by Pd(0)-Catalysed Cross-Coupling Reactions

Universität Rostock, 2011

https://doi.org/10.18453/rosdok_id00000953

Abstract: Salicylates, 3-aryl-3,4-dihydroisocoumarins and sterically encumbered and functionalized biaryls were synthesized using 1,3-bis(silyl enol ethers) by TiCl4-mediated regioselective [3+3] cyclocondensation strategy. While functionalized fluoranthenes, 4-aryl-1-bromo-2-trifluoromethylbenzenes, 2,5-diaryl-1-trifluoromethylbenzene and terphenyls and tetraaryl-p-benzoquinones were synthesized by palladium(0)-catalyzed Heck and Suzuki cross coupling reactions.

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