goto contents


Qiquan Luo

Theoretical study of formic acid dehydrogenation and full hydrogenation of acrolein

Universität Rostock, 2013

https://doi.org/10.18453/rosdok_id00001202

Abstract: This dissertation focused mainly on theoretical study of formic acid (HCOOH) decomposition on the Ni(111), Pd(111), Ni(211), Pd(211), Pt(211) and Mo2C(101) surfaces, since formic acid has been considered as one of potential materials in hydrogen storage and generation. The formate route plays the dominating role in formic acid decomposition; and the rate-determining step is the dissociation of formate into surface CO2 and H. In addition, the Ni(111) surface was also employed to investigate the mechanism of full acrolein hydrogenation.

doctoral thesis   free access    


Portals

OPACGVKDataCite Commons

Rights

all rights reserved

This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz).