| title: |
| Theoretical study of formic acid dehydrogenation and full hydrogenation of acrolein |
|
| contributing persons: |
| Qiquan Luo[VerfasserIn] |
 |
1038176794 |
| Haijun Jiao
, PD Dr.[AkademischeR BetreuerIn] |
|
131449311 |
|
Leibniz-Institut für Katalyse e. V., Universität Rostock |
| Ralf Ludwig
, Prof. Dr.[AkademischeR BetreuerIn] |
|
136437524 |
|
Institut für Chemie, Universität Rostock |
|
| contributing corporate bodies: |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
| |
| abstract: |
|
This dissertation focused mainly on theoretical study of formic acid (HCOOH) decomposition
on the Ni(111), Pd(111), Ni(211), Pd(211), Pt(211) and Mo2C(101) surfaces, since formic
acid has been considered as one of potential materials in hydrogen storage and generation.
The formate route plays the dominating role in formic acid decomposition; and the
rate-determining step is the dissociation of formate into surface CO2 and H. In addition,
the Ni(111) surface was also employed to investigate the mechanism of full acrolein
hydrogenation.
[English] |
|
| document type: |
|
| institution: |
| Faculty of Mathematics and Natural Sciences |
|
| language: |
|
| subject class (DDC): |
| 540 Chemistry & allied sciences |
|
| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2013
|
|
| |
| identifiers: |
|
| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
| RosDok id: |
rosdok_disshab_0000001023 |
| created / modified: |
22.08.2013 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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