Thermodynamic properties of ionic liquids

Andrei Yermalayeu

doi:10.18453/rosdok_id00001269

Andrei Yermalayeu

Thermodynamic properties of ionic liquids

Universität Rostock, 2014

https://doi.org/10.18453/rosdok_id00001269

Abstract: Vaporization enthalpies of ILs were derived by direct methods (quartz crystal microbalance and thermogravimetry), and indirect methods (combustion, reaction, and solution calorimetry combined with the quantum chemical calculations). Three independent procedures were suggested for the adjustment of vaporization enthalpies to the 298 K. Obtained consistent experimental data was used for evaluation of structure-property relations in ILs. It was established that ILs generally obey group additivity rules. A group-contribution method was developed for prediction of vaporization enthalpies of ILs.

doctoral thesis free access

title:

Thermodynamic properties of ionic liquids

contributing persons:

Andrei Yermalayeu[VerfasserIn]
	1046173200
Sergey Verevkin , Prof. Dr.[AkademischeR BetreuerIn]
	132905841
	Universität Rostock, Institut für Chemie
Ingo Krossing , Prof. Dr.[AkademischeR BetreuerIn]
	11808125X
	Universität Freiburg, Institut für Anorganische und Analytische Chemie

contributing corporate bodies:

Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

abstract:

Vaporization enthalpies of ILs were derived by direct methods (quartz crystal microbalance and thermogravimetry), and indirect methods (combustion, reaction, and solution calorimetry combined with the quantum chemical calculations). Three independent procedures were suggested for the adjustment of vaporization enthalpies to the 298 K. Obtained consistent experimental data was used for evaluation of structure-property relations in ILs. It was established that ILs generally obey group additivity rules. A group-contribution method was developed for prediction of vaporization enthalpies of ILs. [English]

document type:

doctoral thesis

institution:

Faculty of Mathematics and Natural Sciences

language:

English

subject class (DDC):

540 Chemistry & allied sciences

publication /
production:

Rostock: Universität Rostock

2014

identifiers: