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Karolin Kral

Neue asymmetrische cobaltkatalysierte [2+2+2]-Cycloadditionen und Stabilitätsuntersuchungen an der neugebildeten chiralen Heterobiarylachse

Universität Rostock, 2014

Abstract: This thesis describes the photo-assisted, asymmetric cobalt-catalysed [2+2+2] cycloaddition reaction between nitriles and alkynes and the formation of pyridines. The work focussed on the synthesis of axially chiral 1 aryl-5,6,7,8-tetrahydroisoquinolines and related derivatives. Systematic studies of the stability of the differently substituted chiral biaryls were performed by dynamic chiral HPLC.

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