title: |
Synthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2]
cycloaddition reactions |
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contributing persons: |
Indre Thiel[VerfasserIn] |
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1047534681 |
Uwe Rosenthal
, Prof. Dr. rer. nat. habil.[AkademischeR BetreuerIn] |
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14076657X |
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Universität Rostock, Leibniz-Institut für Katalyse e.V. |
Matthias Tamm
, Prof. Dr.[AkademischeR BetreuerIn] |
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Technische Universität Braunschweig, Institut für Anorganische und Analytische Chemie |
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contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of
the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated
that the use of two different ligands – namely an olefin and a phosphite ligand –
proved to be superior to the homoleptic equivalents, providing sufficient activity
in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further
modifications resulted in air-stable and recyclable catalysts, which could be supported
on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2014
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000001113 |
created / modified: |
18.02.2014 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |