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Bianca Blankschein

Siliciumbasierte CN-Liganden und deren Anwendung in der Synthese von Koordinationspolymeren

Universität Rostock, 2014

Abstract: In this thesis different coordination polymers with silver and copper(II) salts and phenylnitrilesilanes as ligands were prepared and investigated. First a general and simplified synthesis for the ligands R4-nSi(p-C6H4CN)n was developed based on a known synthesis from literature. In addition to the three known compounds (Me4-nSi(p-C6H4CN)n; for n = 1, 2, 4) four novel silanes and the analogue germane Ge(p-C6H4CN)4 could be prepared. Utilizing these ligands 13 novel silver coordination compounds and five novel copper(II) coordination compounds were synthesized.

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