| title: |
| Development of palladium nanoparticles based catalysts for aerobic oxidation of 5-hydroxymethylfurfural
and glycerol |
|
| contributing persons: |
| Baraa Siyo[VerfasserIn] |
 |
1060564440 |
| Peter Langer
, Prof. Dr.[AkademischeR BetreuerIn] |
|
132314614 |
|
Universität Rostock, Institut für Chemie, Abteilung Organische Chemie |
| Johannes Gerardus de Vries
, Prof. Dr.[AkademischeR BetreuerIn] |
|
Universität Rostock, Leibniz Institut für Katalyse |
|
| contributing corporate bodies: |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
| |
| abstract: |
|
Palladium nanoparticles were synthesized by the polyol method. The prepared NPs were
deposited onto supports and applied in 5-hydroxymethylfurfural (HMF) and glycerol
(GLY) oxidation. A high yield of 2,5-furandicarboxylic acid > 90 % connected with
a relatively stable catalytic performance was obtained by HMF oxidation on a Pd/ZrO2/La2O3.
A lactic acid yield of 75 % was obtained by GLY oxidation on a Pd-Ag/TiO2 which showed
also a stable catalytic performance when the catalyst was recycled. The prepared catalysts
were characterized by various methods before and after the oxidation reactions.
[English] |
|
| document type: |
|
| institution: |
| Faculty of Mathematics and Natural Sciences |
|
| language: |
|
| subject class (DDC): |
| 540 Chemistry & allied sciences |
|
| |
publication /
production: |
|
Rostock: Universität Rostock
|
|
2014
|
|
| |
| identifiers: |
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| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
| RosDok id: |
rosdok_disshab_0000001249 |
| created / modified: |
11.11.2014 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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