title: |
Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted
heteroarenes and further transformations of nitro group |
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contributing persons: |
Ashot Gevorgyan[VerfasserIn] |
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1079688854 |
Peter Langer
, Prof. Dr.[AkademischeR BetreuerIn] |
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132314614 |
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Universität Rostock, Institut für Chemie |
Maison Wolfgang
, Prof. Dr.[AkademischeR BetreuerIn] |
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Universität Hamburg, Fachbereich Chemie, Medizinische/Pharmazeutische Chemie |
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contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
The present work aimed to study the transition-metal-catalyzed direct C-H arylation
of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives,
4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and
thiophene. Under optimized reaction conditions a wide range of coupling partners were
perfectly tolerated. Additional empirical studies indicated that the nitro group has
influence on the regioselectivity of the reactions. In addition, the multipurpose
nature of nitro group as a versatile directing group was explored.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2015
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000001467 |
created / modified: |
08.12.2015 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |