title: |
Tetracyanidoborates with triply charged rare earth metal cations and their optical
properties |
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contributing persons: |
Liisa Hackbarth[VerfasserIn] |
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1079688382 |
Martin Köckerling
, Prof. Dr. rer. nat.[AkademischeR BetreuerIn] |
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Universität Rostock, Institut für Chemie |
Stefan Lochbrunner
, Prof. Dr. rer. nat.[AkademischeR BetreuerIn] |
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Universität Rostock, Institut für Physik |
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contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
A new group of tetracyanidoborates - tetracyanidoborates with trivalent rare earth
metal cations - was synthesized. The rare earth tetracyanidoborates form isostructural
groups, e.g. [LRE(H2O)5][B(CN)4]3•0.5 H2O, with LRE3+ = La, Ce, Pr, Nd, Sm, Eu, Gd
and [HRE(H2O)7][B(CN)4]3 with HRE3+ = Tb, Dy, Ho, Er, Tm, Yb, Lu and Y. These tetracyanidoborates
exhibit rare earth cation specific luminescence properties which are improved by the
tetracyanidoborate anion. Therefore, the tetracyanidoborates with trivalent rare earth
metal cations could have possible applications in phosphors.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2015
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000001469 |
created / modified: |
08.12.2015 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |