Catalysis with porous MOFs : structure-catalytic property-relationships in the hydroformylation of olefins over Rh supported metal-organic frameworks

Toan Van Vu

doi:10.18453/rosdok_id00001665

Toan Van Vu

Catalysis with porous MOFs : structure-catalytic property-relationships in the hydroformylation of olefins over Rh supported metal-organic frameworks

Universität Rostock, 2015

https://doi.org/10.18453/rosdok_id00001665

Abstract: It deals with preparation, characterization, and catalytic testing of Rh supported catalysts based on MOFs using hydroformylation as a model reaction. The influence of the MOF support on the catalytic performance (Structure-Catalytic Property-Relationships) is emphasized. Different MOF structures and pore sizes were synthesized, Rh immobilized, characterized, and tested. Results show that single site catalysts are achieved. The catalytic performance is affected by the structure, texture, and porosity of the MOF support. The linker orientation is of importance leading to single-file diffusion.

Dissertation Freier Zugang

Titel:

Catalysis with porous MOFs: structure-catalytic property-relationships in the hydroformylation of olefins over Rh supported metal-organic frameworks

Beteiligte Personen:

Toan Van Vu[VerfasserIn]
	1057858439
Axel Schulz , Prof. Dr. rer. nat. habil.[AkademischeR BetreuerIn]
	141478187
	University of Rostock, Institute of Chemistry
Udo Kragl , Prof. Dr. rer. nat.[AkademischeR BetreuerIn]
	131893351
	University of Rostock, Institute of Chemistry

Beteiligte Körperschaften:

Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

It deals with preparation, characterization, and catalytic testing of Rh supported catalysts based on MOFs using hydroformylation as a model reaction. The influence of the MOF support on the catalytic performance (Structure-Catalytic Property-Relationships) is emphasized. Different MOF structures and pore sizes were synthesized, Rh immobilized, characterized, and tested. Results show that single site catalysts are achieved. The catalytic performance is affected by the structure, texture, and porosity of the MOF support. The linker orientation is of importance leading to single-file diffusion. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Veröffentlichung /
Entstehung:

Rostock

Rostock: Universität Rostock

2015