title: |
Catalysis with porous MOFs: structure-catalytic property-relationships in the hydroformylation
of olefins over Rh supported metal-organic frameworks |
|
contributing persons: |
Toan Van Vu[VerfasserIn] |
|
1057858439 |
Axel Schulz
, Prof. Dr. rer. nat. habil.[AkademischeR BetreuerIn] |
|
141478187 |
|
University of Rostock, Institute of Chemistry |
Udo Kragl
, Prof. Dr. rer. nat.[AkademischeR BetreuerIn] |
|
131893351 |
|
University of Rostock, Institute of Chemistry |
|
contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
|
abstract: |
It deals with preparation, characterization, and catalytic testing of Rh supported
catalysts based on MOFs using hydroformylation as a model reaction. The influence
of the MOF support on the catalytic performance (Structure-Catalytic Property-Relationships)
is emphasized. Different MOF structures and pore sizes were synthesized, Rh immobilized,
characterized, and tested. Results show that single site catalysts are achieved. The
catalytic performance is affected by the structure, texture, and porosity of the MOF
support. The linker orientation is of importance leading to single-file diffusion.
[English] |
|
document type: |
|
institution: |
Faculty of Mathematics and Natural Sciences |
|
language: |
|
subject class (DDC): |
540 Chemistry & allied sciences |
|
|
publication / production: |
Rostock
Rostock: Universität Rostock
|
2015
|
|
|
identifiers: |
|
|
access condition: |
|
license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
RosDok id: |
rosdok_disshab_0000001486 |
created / modified: |
15.12.2015 / 08.08.2023
|
metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |