Universität Rostock, 2016
Abstract: This thesis deals with the synthesis and characterization of several [PF6-n(CN)n]- based compounds (n = 1 – 6) using self-developed synthetic routes. The very mild Lewis-acid catalysis leads for [PF6-n(CN)n]- (n = 1 - 4) units to a variety of new ionic liquids and building blocks for coordination polymers. Furthermore, the catalytic synthesis is adapted for the synthesis of [BF4-n(CN)n]- anions resulting in a new and efficient synthetic approach towards the often used [B(CN)4]- anion.
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