Synthesis and characterization of new CN-based transition metal complexes

Omar Mowafaq Younis Al-Ramadhani

doi:10.18453/rosdok_id00001837

Omar Mowafaq Younis Al-Ramadhani

Synthesis and characterization of new CN-based transition metal complexes

Universität Rostock, 2016

https://doi.org/10.18453/rosdok_id00001837

Abstract: In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized.

Dissertation Freier Zugang

Titel:

Synthesis and characterization of new CN-based transition metal complexes

Beteiligte Personen:

Omar Mowafaq Younis Al-Ramadhani[VerfasserIn]
	1123243573
Axel Schulz[GutachterIn]
	0000-0001-9060-7065
	141478187
Uwe Rosenthal[GutachterIn]
	14076657X

Beteiligte Körperschaften:

Universität Rostock[Grad-verleihende Institution]
	38329-6
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Veröffentlichung /
Entstehung:

Rostock

Rostock: Universität Rostock

2016