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Anne-Kristin Rölke

Synthese eines hypersilylstabilisierten Phosphorbiradikaloids sowie Untersuchungen zur Reaktivität

Universität Rostock, 2017

https://doi.org/10.18453/rosdok_id00001855

Abstract: In this thesis, the results of the synthesis and reactivity study of a silylated phosphorous centered biradicaloid ([P(μ-NHyp)]2) are presented. Reactivity investigations of [P(μ-NHyp)]2 led to the formation and isolation of several new cage compounds. The variation of the organic substituent from terphenyl to hypersilyl depending on the stability of the biradicaloid and the larger charge transfer of the hypersilyl group was in the focus of this work. The activation of small molecules as well as the activation of double-bond and triple-bond containing systems was shown.

doctoral thesis   free access